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Certified efficiency of halogenated Pb-perovskite solar cells has reached 25.2 %. Because of the Pb usage restriction, researches on Pb free perovskite solar cells have been focused on. Halogenated Sn-perovskite is one of candidates for the Pb-free perovskite solar cells. In spite of the similarities of the electronic properties between Pb-perovskite and Sn-perovskite, the efficiency of the Sn-perovskite solar cell was still about 10%, which is far below that of Pb-perovskite solar cells. We report Ge ion doped Sn-perovskite solar cells (Pb free) with 13% efficiency by optimizing A site cations in ASnI3 composition and surface passivation.
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