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Chalcogenide glasses are known for their large transparency in the mid-infrared and their high non linear optical properties. Different methods have developed to prepare the microstructured chalcogenide preforms and fibers. In this context, various chalcogenide PCFs operating in the MIR range have been elaborated in order to associate the high non-linear properties of these glasses and the original PCF properties. For example, small core fibers have been drawn to enhance the non linearities for telecom applications and generation of supercontinuum sources. In the 2-12 µm window, single mode fibers, polarization maintaining fibers and exposed core fibers have been realized for Gaussian beams propagation and sensors applications.
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