Synthesis and SHG effect of some cyclotriphosphazene derivatives

Yang Xia; Caimao Zhan; Jingui Qin; Daoyu Liu; Baichang Wu; Chuangtian Chen

doi:10.1117/12.318233

14 August 1998 Synthesis and SHG effect of some cyclotriphosphazene derivatives

Yang Xia, Caimao Zhan, Jingui Qin, Daoyu Liu, Baichang Wu, Chuangtian Chen

Proceedings Volume 3556, Electro-Optic and Second Harmonic Generation Materials, Devices, and Applications II; (1998) https://doi.org/10.1117/12.318233
Event: Photonics China '98, 1998, Beijing, China

Abstract

Twenty derivatives of hexachlorocyclotriphosphazene were synthesized by substituted reaction. The structure of the cyclotriphosphazenes were identified by i.r. uv-vis, n.m.r. and elemental analysis, proving that they are fully substituted cyclotriphosphazenes. Kurtz powder determination of SHG showed that two of them displayed SHG effect. X-ray diffraction determination of N₃P₃(OC₆H₄F)₆ is presented to explain SHG effect.

Citation Download Citation

Yang Xia, Caimao Zhan, Jingui Qin, Daoyu Liu, Baichang Wu, and Chuangtian Chen "Synthesis and SHG effect of some cyclotriphosphazene derivatives", Proc. SPIE 3556, Electro-Optic and Second Harmonic Generation Materials, Devices, and Applications II, (14 August 1998); https://doi.org/10.1117/12.318233

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