2 December 2022 Cylindrical transparent conductive oxide-free dye-sensitized solar cells with treated flat titanium sheet
Azwar Hayat, Ajay Kumar Baranwal, Masaki Nakamura, Fujisawa Shigeki, Shyam S. Pandey, Shuzi Hayase
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Abstract

Conventional dye-sensitized solar cells (DSSCs) require two transparent conductive oxide (TCO) glasses as working and counter electrodes and are one of the most costly components posing an appreciable cost burden for production and commercialization. To circumvent this issue, we propose a TCO-free device structure utilizing titanium (Ti) sheets as a substitute for TCO. This back contact device structure not only allows the removal of the costly TCO component from the working electrode but also enhances the extent of photons absorbed by the photoanode. A flat titanium sheet with microholes (FTS-MH) was successfully applied to fabricate cylindrical TCO-free-DSSCs) with a titanium sheet as a back contact electrode. When the H2O2 surface-treated FTS-MH substrate generating dense anatase TiO2 nanosheets was used as a photoanode, there was a pronounced improvement in efficiency from 5.76% to 8.59%. This was mainly attributed to the lower interfacial resistance facilitated by improved electrical contact between the conducting FTS-MH substrate and mesoporous TiO2 layer since enhancement in the dye loading was only 8.6%.

© 2022 Society of Photo-Optical Instrumentation Engineers (SPIE)
Azwar Hayat, Ajay Kumar Baranwal, Masaki Nakamura, Fujisawa Shigeki, Shyam S. Pandey, and Shuzi Hayase "Cylindrical transparent conductive oxide-free dye-sensitized solar cells with treated flat titanium sheet," Journal of Photonics for Energy 12(4), 045502 (2 December 2022). https://doi.org/10.1117/1.JPE.12.045502
Received: 9 April 2022; Accepted: 15 November 2022; Published: 2 December 2022
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Cited by 1 scholarly publication.
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KEYWORDS
Dye sensitized solar cells

Titanium

Dyes

Solar cells

Electrodes

Glasses

Transparent conductors

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