An edge collection function is proposed for characterizing the optical efficiency of an energy-harvesting system that utilizes photoluminescence (PL) in a waveguide. We assume that a single spot in a waveguide is excited and that PL is isotropic. For the photons to be collected by one edge of the waveguide, they must be emitted toward the edge, trapped in the waveguide and they must survive self-absorption on the way. The optical efficiency is formulated as the product of these probabilities. When this function is calculated for every spot on the waveguide and for each wavelength of the PL spectrum, the efficiency of the system is given by superposition. Its validity is checked by a Monte Carlo simulation for the case of no self-absorption loss. In experiment, we fabricate a 5-cm2 waveguide with a thin layer of Lumogen F Red 305 and measure its efficiency by placing a photodiode array in the vicinity of its edge with a small air gap. The formula roughly reproduces the efficiency and its dependency on the position of the excitation spot. This analytical approach allows one to estimate the optical efficiency for an arbitrary incident light distribution with small computational complexity.
We have proposed and demonstrated position-sensitive detectors based on the spectral changes in fluorescent waveguides. The first prototype is a transparent heat-shrink tubing containing an organic luminescent dye at its core. With a laser beam incident on this linear fluorescent tubing, the redshift in the photoluminescence (PL) spectrum observed at its edge increases with the distance from the incident point. The range for position sensing is 2 cm. It is extended to 280 cm by adopting a scintillating fiber in our second experiment. Two-stage conversion enables two-dimensional position detection. We have attached two linear fluorescent tubing to a planar 50 mm × 50 mm × 8 mm fluorescent waveguide. When a laser beam excites the first luminescent material at a single spot in the planer waveguide, PL photons propagate to its edges and excite the second luminescent material in the two linear waveguides. Photon division between these linear waveguides gives the first coordinate. The second coordinate is given by the redshift in the linear waveguides. We have observed that the maximum error in position estimation is 1.5 mm. Unlike the conventional semiconductor technologies, no electronic components are required for the sensor head. This robust technology might be suited for deployment in large-scale harsh environments.
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