Mid-infrared sensing in the broadband spectral region of 5 – 11 𝜇m is suitable for detecting and quantifying multiple trace species. However, the challenge in detection is precise discrimination due to the broad linewidth of molecular transitions of species like methane, nitrous oxide, and other volatile organic compounds. In addition, isotopic transitions are generally weaker, with significant overlap with the neighboring abundant molecular transitions. This paper shows broadband detection of multiple species using an external cavity laser operation in 6 to 11 𝜇m spectral region. We use a combination of Savitzy-Golay filtering and machine learning-based classification to discern weaker rotational vibrational transitions. The proposed scheme is used to denoise and discriminate molecular transition in mid-infrared absorption spectroscopy. We show that an optimized S-G framework can be used by choosing a selected frame length determined by the adaptive learning outcome with low loss. We show that an ML-based adaptive SV filter can effectively suppress mod-hop (or any other instrumental-related effects and drifts). This is achieved by appropriately training the absorption spectroscopy signals with a calibrated reference in a (gaussian or thermal) noisy environment.
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