We present previously unreported properties of the organic molecular dye compound, 2,3,7,8-tetracyano-5,10-dimethyl-5,10-dihydrodipyrazino[2,3-b:2’,3’-e]pyrazine (DMTC-pyrazine) (CAS Reg. No. 150960-11-5), including photophysical properties with particular emphasis on optical waveguiding. We show that DMTC-pyrazine can self-assemble into monoclinic crystals that are thermally stable over 300°C. Through shape-engineering, optimized growth conditions produced high yields of nanofiber (aspect ratio >6) crystals. No photobleaching of this dye was observed in air even after hours of on-resonant illumination. Excitation of photoluminescence within the DMTC-pyrazine nanofibers propagates in tightly confined guided modes (up to 25 μm). The finesse, end-facet reflectance, and group refractive index of nanofiber DMTC-pyrazine Fabry-Pérot cavities are reported.
Experiments were conducted to demonstrate a material with epsilon near zero (ENZ). Dimensions estimated by effective medium theory guided the fabrication of nanolaminate composites of silver and amorphous polycarbonate. This approach ensures that the ordinary component (not the extraordinary component) of the relative permittivity of a uniaxial material equals zero. The nanolaminates were characterized for optical properties using spectroscopic ellipsometry, reflectance, and transmittance. Simulations using both, a new scattering retrieval method, and an effective-medium approximation (EMA) were compared to the experimental results. These results indicate that nanolaminates should enable further exploration into the new optical phenomena predicted for ENZ materials.
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