Paper
10 April 1989 Direct Writing Of Microcircuits By Laser-Assisted Processing Of Polymers
Christian Decker
Author Affiliations +
Proceedings Volume 1022, Laser Assisted Processing; (1989) https://doi.org/10.1117/12.950111
Event: 1988 International Congress on Optical Science and Engineering, 1988, Hamburg, Germany
Abstract
A new method has been developed to produce conducting materials by surface chemical processing of a chlorinated polymer assisted by a CW laser. Polyvinylchloride (PVC) was first functionalized in order to absorb the 488.1 nm emission line of an argon ion laser. A short exposure of the polymer film to a 1 W laser beam, in the presence of air, leads to a complete removal of the chlorine and hydrogen atoms from the PVC backbone, with formation of a purely carbon material. The latter was shown to contain mainly graphite-type structures which are able to carry electrons, the electrical conductivity of the final product being comparable to that of graphite. Because of the high threshold energy of this solid state reaction, conventional radiation proved unable to induce the graphitization of PVC that occured within milliseconds under laser exposure, thus illustrating the unique possibilities of lasers for performing specific chemical reactions. By focusing the laser beam down into the micronic range, complex conductive patterns were directly drawn onto the photosensitive substrate at high speed. For practical applications of this laser writing technology in microelectronics, the delicate patterns were covered by a protective coating, using a photosensitive acrylic resin that hardens instantly under laser exposure, without affecting the electrical properties of the microcircuit.
© (1989) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Christian Decker "Direct Writing Of Microcircuits By Laser-Assisted Processing Of Polymers", Proc. SPIE 1022, Laser Assisted Processing, (10 April 1989); https://doi.org/10.1117/12.950111
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Cited by 1 scholarly publication and 2 patents.
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KEYWORDS
Chlorine

Polymers

Carbon

Laser processing

Electrons

Laser irradiation

Coating

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