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The influence of the polytypical structure of GaSe on the shape of the EPR spectra of the gadolinium impurity in the Gd3+ state has been investigated. It is shown that in a layered crystal at impurity concentration of about 1018 cm-3 at least
three types of paramagnetic centers appear. The presence of nonequivalent positions of the Gd3+ ion is explained by the presence of polytypic modifications in GaSe. It was revealed that the introduction of a paramagnetic impurity into the crystal significantly expands the NQR spectrum.
Andriy Samila,Galina Lastivka,Alexander Khandozhko, andZahar Kovalyuk
"The EPR and NQR in layered crystal of GaSe: Gd", Proc. SPIE 11369, Fourteenth International Conference on Correlation Optics, 1136919 (6 February 2020); https://doi.org/10.1117/12.2541620
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Andriy Samila, Galina Lastivka, Alexander Khandozhko, Zahar Kovalyuk, "The EPR and NQR in layered crystal of GaSe: Gd," Proc. SPIE 11369, Fourteenth International Conference on Correlation Optics, 1136919 (6 February 2020); https://doi.org/10.1117/12.2541620