Presentation
1 August 2021 Direct quantification of quasi-Fermi level splitting in organic thin film devices
Author Affiliations +
Abstract
Non-radiative losses to the open-circuit voltage are a primary factor in limiting the power conversion efficiency of organic photovoltaic solar cells. The dominate non-radiative loss is intrinsic to the active layer which, along with the thermodynamic limit to the open-circuit voltage, define the quasi-Fermi level splitting (QFLS). Quantification of the QFLS in organic photovoltaic devices is challenging due to the excitonic nature of photoexcitation and device-related non-radiative losses. In this presentation I will outline an experimental approach based on electro-modulated photoluminescence to quantify the QFLS in organic solar cells. Drift-diffusion simulations are used to verify the accuracy of the method, while state-of-the art PM6:Y6 solar cells are created with varying non-radiative losses. This method quantifies the QFLS in organic photovoltaics, fully characterizing the magnitude of different contributions to the non-radiative losses of the open-circuit voltage.
Conference Presentation
© (2021) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Drew Riley, Oskar J. Sandberg, Nora M. Wilson, Wei Li, Stefan Zeiske, Nasim Zarrabi, Paul Meredith, Ronald Osterbacka, and Ardalan Armin "Direct quantification of quasi-Fermi level splitting in organic thin film devices", Proc. SPIE 11809, Organic, Hybrid, and Perovskite Photovoltaics XXII, 118090A (1 August 2021); https://doi.org/10.1117/12.2595586
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KEYWORDS
Organic photovoltaics

Solar cells

Thin film devices

Light emitting diodes

Luminescence

Photodetectors

Thermodynamics

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