A study on graphene analogue using Fe©B6H6 molecular unit

Chao Wang; Jianhua Hou; Qian Duan

doi:10.1117/12.2674155

9 March 2023 A study on graphene analogue using Fe©B₆H₆ molecular unit

Chao Wang, Jianhua Hou, Qian Duan

Proceedings Volume 12600, International Conference on Optoelectronic Materials and Devices (ICOMD 2022); 126000M (2023) https://doi.org/10.1117/12.2674155
Event: 2022 International Conference on Optoelectronic Materials and Devices, 2022, Chongqing, China

Abstract

We can propose constructing a graphene resemblance, that is, doped boron sheet, with the planate ring-type Fe©B₆H₆ cluster as the building block. We explored the idea of using the clusters as building blocks by examining the geometric and electronic structures of its dimer and trimer and their dimerization. To our knowledge, there have been no reports on the creation of doped boron sheets using cluster aggregates. We propose a dehydrogenation route to polymerization that could result in the preparation of a boron sheet with hexagonal holes similar to graphene. The holes would be partially and uniformly filled by Fe atoms, resulting in uniform chemical doping and a high hexagonal-hole density close to that of graphene. This could provide a new type of cluster-assembled material for experimentation by chemists seeking to construct a graphene analogue.

Citation Download Citation

Chao Wang, Jianhua Hou, and Qian Duan "A study on graphene analogue using Fe©B₆H₆ molecular unit", Proc. SPIE 12600, International Conference on Optoelectronic Materials and Devices (ICOMD 2022), 126000M (9 March 2023); https://doi.org/10.1117/12.2674155

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