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We discuss possible mechanisms of doping induced volume change in conjugated polymers with reference to the case of poly(3,4- ethylenedioxythiophene) (PEDOT). This material has been studied in two forms; as well ordered paracrystalline material and in the form of a water swollen conducting hydrogel. Structural and electrochemical studies are discussed.
Olle Inganas,Soumyadeb Ghosh,Emil J. Samuelsen,Knut E. Aasmundtveit,Leif A. A. Pettersson, andTomas Johansson
"Model polymers for polymer actuators", Proc. SPIE 3669, Smart Structures and Materials 1999: Electroactive Polymer Actuators and Devices, (28 May 1999); https://doi.org/10.1117/12.349712
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Olle Inganas, Soumyadeb Ghosh, Emil J. Samuelsen, Knut E. Aasmundtveit, Leif A. A. Pettersson, Tomas Johansson, "Model polymers for polymer actuators," Proc. SPIE 3669, Smart Structures and Materials 1999: Electroactive Polymer Actuators and Devices, (28 May 1999); https://doi.org/10.1117/12.349712