Spectro-luminescent characteristics were determined for LaSc3(BO3)4-crystals, activated by ions of the ytterbium and the erbium. Quantum efficiency of nonradiative transfer from the ions Yb3+ to the Er3+ is closed to 80% for concentration of ions [Yb] equals 1021 cm-3, [Er] equals 5 (DOT) 1019 cm-3. Quantum efficiency of energy transmission from the Cr3+ to the Er3+ is about 90%. Having achieved population inversion in the Er-ions the efficiency of energy transmission decay to 70%. We have fulfilled comparison of generation properties for lasers with active elements made of LSB-crystal, that contents [Cr3+] equals 0.5 at.%, [Yb3+] equals 10 at.%, [Er3+] equals 0.5 at.%, and phosphate glass that contents [Cr3+] equals 0.3 wt.%, [Yb3+] equals 20 wt.%, [Er3+] equals 0.2 wt.%.
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