Development of electrochemical sensors for trace detection of explosives and for the detection of chemical warfare agents

T. Berger; H. Ziegler; Michael Krausa

doi:10.1117/12.396272

22 August 2000 Development of electrochemical sensors for trace detection of explosives and for the detection of chemical warfare agents

T. Berger, H. Ziegler, Michael Krausa

Author Affiliations +

Proceedings Volume 4038, Detection and Remediation Technologies for Mines and Minelike Targets V; (2000) https://doi.org/10.1117/12.396272
Event: AeroSense 2000, 2000, Orlando, FL, United States

Abstract

A huge number of chemical sensors are based on electrochemical measurement methods. Particularly amperometric sensorsystems are employed for the fast detection of pollutants in industry and environment as well as for analytic systems in the medical diagnosis. The large number of different applications of electrochemical sensors is based on the high sensitivity of electrochemical methods and on the wide of possibilities to enhance the selectivity by variation of electrochemical and chemical parameters. Besides this, electrochemical sensorsystems are frequently simple to operate, transportable and cheap. Up to now the electrochemical method of cyclic voltammetry is used only seldom for sensors. Clearly the efficiency of cyclic voltammetry can be seen at the sensorsystem for the detection of nitro- and aminotoluenes in solids and waters as presented here. The potentiodynamic sensors system can be employed for the fast and easy risk estimation of contaminated areas. Because of the high sensitivity of electrochemical methods the detection of chemical substances with a low vapor pressure is possible also. The vapor pressure of TNT at room temperature is 7 ppb for instances. With a special electrochemical set-up we were able to measure TNT approximately 10 cm above a TNT-sample. In addition we were able to estimate TNT in the gaseous phase approximately 10 cm above a real plastic mine. Therefore it seems to be possible to develop an electrochemical mien detection. Moreover, we present that the electrochemical detection of RDX, HMX and chemical warfare agents is also possible.

Citation Download Citation

T. Berger, H. Ziegler, and Michael Krausa "Development of electrochemical sensors for trace detection of explosives and for the detection of chemical warfare agents", Proc. SPIE 4038, Detection and Remediation Technologies for Mines and Minelike Targets V, (22 August 2000); https://doi.org/10.1117/12.396272

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