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The thionine photoreduction kinetics in film of polyvinyl-alcohol is proposed to describe as the consecutive reaction with one equilibrium stage: (formula given in paper). To given scheme the values of k2 = (3,60 ± 0,26)•10-3 s-1 and k3=(2,93 ± 0,56)•10-3 s-1 are determined. The values of k1 constant demonstrate the linear dependence on laser intensity.
D. A. Razdobreev,Yu. D. Lantukh, andA. V. Stryapkov
"Investigation of thionine photobleaching under He-Ne laser irradiation", Proc. SPIE 5447, Lasers for Measurements and Information Transfer 2004, 544718 (16 February 2005); https://doi.org/10.1117/12.610511
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D. A. Razdobreev, Yu. D. Lantukh, A. V. Stryapkov, "Investigation of thionine photobleaching under He-Ne laser irradiation," Proc. SPIE 5447, Lasers for Measurements and Information Transfer 2004, 544718 (16 February 2005); https://doi.org/10.1117/12.610511