Time-resolved Infrared Studies Of Coordinatively Unsaturated Metal Carbonyl Species

Avtar S. Nazran; Michel Drouin; David M. Rayner; Peter A. Hackett

doi:10.1117/12.970890

20 December 1985 Time-resolved Infrared Studies Of Coordinatively Unsaturated Metal Carbonyl Species

Avtar S. Nazran, Michel Drouin, David M. Rayner, Peter A. Hackett

Proceedings Volume 0553, Fourier and Computerized Infrared Spectroscopy; (1985) https://doi.org/10.1117/12.970890
Event: 1985 International Conference on Fourier and Computerized Infrared Spectroscopy, 1985, Ottawa, Canada

Abstract

Fast laser based time-resolved infrared absorption spectroscopy has been applied to the study of the ultraviolet photolysis of the pseudo-nickel carbonyl, tricarbonylnitrosocobalt. The kinetics of the disappearance of the starting molecule and the formation of a coordinatively unsaturated cobalt species, tentatively assigned as Co(C0)2, have been observed. Rate constants for the secondary reaction of this species with the parent compound, and with CO, have been determined. A reaction mechanism is proposed.

Citation Download Citation

Avtar S. Nazran, Michel Drouin, David M. Rayner, and Peter A. Hackett "Time-resolved Infrared Studies Of Coordinatively Unsaturated Metal Carbonyl Species", Proc. SPIE 0553, Fourier and Computerized Infrared Spectroscopy, (20 December 1985); https://doi.org/10.1117/12.970890

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