Laser IR spectroscopy of HeH+ and H+3: new approaches to standard theory and experiment

Gleb E. Kulikov; Vladimir M. Mikhailov

doi:10.1117/12.675461

21 April 2006 Laser IR spectroscopy of HeH⁺ and H⁺₃: new approaches to standard theory and experiment

Gleb E. Kulikov, Vladimir M. Mikhailov

Proceedings Volume 6160, Twelfth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics; 61601U (2006) https://doi.org/10.1117/12.675461
Event: Twelfth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics, 2005, Tomsk, Russian Federation

Abstract

The protonited helium molecular ion HeH⁺ and the hydrogen molecular ion H⁺₃ are investigated by the methods of laser JR spectroscopy in near JR region.The two types of lasers are used in experimental setup for planned experimental investigation of HeH+ and H⁺₃. The two modern theoretical conceptions are applied for the first time for the construction of effective Hamiltonian and effective dipole moments for ions under consideration: the linked ordered schemas of vibrational - rotational interactions and pseudoangular momentum for double degenerated mode of H⁺₃. Nonlinear sequence transformation methods are applicated for analysis of rotational and vibrational dependencies of effective Hamiltonian and effective dipole moments.

Citation Download Citation

Gleb E. Kulikov and Vladimir M. Mikhailov "Laser IR spectroscopy of HeH⁺ and H⁺₃: new approaches to standard theory and experiment", Proc. SPIE 6160, Twelfth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics, 61601U (21 April 2006); https://doi.org/10.1117/12.675461

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