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The ytterbium-doped crystals emitting around 1 μm under laser-diode pumping between 900-980 nm have received an
increasing interest in recent years as solid-state laser materials for high power or ultra-fast lasers. In this paper, our main
objective is to contribute to Yb3+-doped fluorides mainly on CaF2 cubic host which are characterized by a high value of
the thermal conductivity (9.5 W m-1 K-1) as high as YAG. Yb3+-doped CaF2, mono-doped and concentration gradient
fibres were grown by both, the laser heated pedestal growth (LHPG) method and by the Czochralski method. Concerning
Yb3+ excited state dynamics, the concentration dependence of the 2F5/2 decay time shows a competition between self-trapping
and self-quenching processes. Main parameters useful for a theoretical approach of laser potentiality will be
given and laser emission under InGaAs laser-diode pumping will be shown.
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G. Boulon, M. Ito, Y. Guyot, C. Goutaudier, A. Brenier, A. Jouini, H. Sato, T. Fukuda, "Yb3+-doped CaF2 cubic fluoride crystal: spectroscopic properties, concentration quenching analysis, and laser optimization," Proc. SPIE 6785, ROMOPTO 2006: Eighth Conference on Optics, 678503 (1 August 2007); https://doi.org/10.1117/12.755474