Paper
27 August 2009 Fabrication and optimization of P3HT:PCBM organic photovoltaic devices
James W. Kingsley, Adam Green, David G. Lidzey
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Abstract
We explore the optimization of organic photovoltaic (OPV) devices based on a thin-film blend of the polymer poly(3-hexyl thiophene) [P3HT] and the fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester [PCBM]. In particular, we address the preparation of the PEDOT:PSS device anode, the composition, thickness and thermal treatment of the active semiconductor layer along with the effect of presence of self-assembled P3HT nanofibres. We also investigate the use of materials such as glycerol and oleic acid dispersed into the PEDOT:PSS and P3HT/PCBM layers respectively to improve the power conversion efficiency (PCE) of the device. Our optimization protocol results in the creation of OPV devices having power conversion efficiencies (PCEs) of up to 4.5%.
© (2009) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
James W. Kingsley, Adam Green, and David G. Lidzey "Fabrication and optimization of P3HT:PCBM organic photovoltaic devices", Proc. SPIE 7416, Organic Photovoltaics X, 74160T (27 August 2009); https://doi.org/10.1117/12.829178
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Cited by 8 scholarly publications.
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KEYWORDS
Annealing

Organic photovoltaics

Polymers

Semiconductors

Absorption

Control systems

External quantum efficiency

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