Scanning Raman spectroscopy of nanostructured graphene: doping due to presence of edges

Stefanie Heydrich; Michael Hirmer; Tobias Korn; Jonathan Eroms; Dieter Weiss; Christian Schüller

doi:10.1117/12.892164

19 September 2011 Scanning Raman spectroscopy of nanostructured graphene: doping due to presence of edges

Stefanie Heydrich, Michael Hirmer, Tobias Korn, Jonathan Eroms, Dieter Weiss, Christian Schüller

Proceedings Volume 8101, Carbon Nanotubes, Graphene, and Associated Devices IV; 810109 (2011) https://doi.org/10.1117/12.892164
Event: SPIE NanoScience + Engineering, 2011, San Diego, California, United States

Abstract

We report about scanning Raman experiments on, both, as deposited and nano-structured graphene flakes. The Raman scans allow us to extract spatially resolved information about frequencies, intensities and linewidths of the observed phonon modes. In nano-structured single-layer flakes, where periodic arrays of holes (antidots) were fabricated by electron-beam lithography and subsequent etching, we find a systematic dependence of the phonon frequencies, intensities and linewidths on the periods and hole sizes of the nano-patterned regions. A systematic shift of the G mode frequency evidences a doping effect in the nano-patterned regions. In order to calibrate the doping dependence of the G mode phonon frequency, we have investigated the position and linewidth of this mode in a gated single-layer flake. With this calibration, we can quantitatively determine the doping level, which is introduced via preparation of the periodic hole arrays into the samples. A comparison of G and 2D mode frequencies allows us to identify the doping to be of p-type.

Citation Download Citation

Stefanie Heydrich, Michael Hirmer, Tobias Korn, Jonathan Eroms, Dieter Weiss, and Christian Schüller "Scanning Raman spectroscopy of nanostructured graphene: doping due to presence of edges", Proc. SPIE 8101, Carbon Nanotubes, Graphene, and Associated Devices IV, 810109 (19 September 2011); https://doi.org/10.1117/12.892164

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KEYWORDS

Graphene

Raman spectroscopy

Doping

Phonons

Calibration

Lithography

Microscopes

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