Optical nonlinearity and power limiting in organic molecules and nanocomposites

Reji Philip; Jayan Thomas

doi:10.1117/12.897117

16 September 2011 Optical nonlinearity and power limiting in organic molecules and nanocomposites

Reji Philip, Jayan Thomas

Proceedings Volume 8113, Linear and Nonlinear Optics of Organic Materials XI; 81130J (2011) https://doi.org/10.1117/12.897117
Event: SPIE Photonic Devices + Applications, 2011, San Diego, California, United States

Abstract

Nonlinear optical transmission in materials has several applications including laser mode-locking, pulse shaping, optical bistability, optical switching, and optical power limiting. Organic molecules suitable for functionalization have been extensively investigated for their third order nonlinearities. We have measured the optical nonlinearity of different novel organic and composite systems including nanocomposite polymer films of Au, Ag and Pt, Organic ionic crystals (pyridinium and quinolinium salts), Au-alkanethiol clusters, thiophene based polymers, and Schiff base complexes, using the z-scan and degenerate four wave mixing techniques, employing laser pulses of nanosecond and femtosecond durations respectively. Most of these materials are found to be efficient optical power limiters under our excitation conditions, and their nonlinear extinction coefficients have been calculated. Enhancement in the optical nonlinearity was sometimes obtained even by mixing of two organic media. From degenerate four wave mixing experiments, the third order nonlinear susceptibility χ⁽³⁾ and figure of merit χ⁽³⁾/α values also have been determined for some of these materials. The above experiments conducted in a large number of organic and composite materials unravel the potential of these media for diverse photonic applications.

Citation Download Citation

Reji Philip and Jayan Thomas "Optical nonlinearity and power limiting in organic molecules and nanocomposites", Proc. SPIE 8113, Linear and Nonlinear Optics of Organic Materials XI, 81130J (16 September 2011); https://doi.org/10.1117/12.897117

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