Two hundred and one firings of three 152 mm howitzer munitions were observed to characterize firing signatures of a
large caliber gun. Muzzle blast expansion was observed with high-speed (1600 Hz) optical imagery. The trajectory of the
blast front was well approximated by a modified point-blast model described by constant rate of energy deposition.
Visible and near-infrared (450 - 850 nm) spectra of secondary combustion were acquired at ~0.75 nm spectral resolution
and depict strong contaminant emissions including Li, Na, K, Cu, and Ca. The O2 (X→b) absorption band is evident in
the blue wing of the potassium D lines and was used for monocular passive ranging accurate to within 4 - 9%. Timeresolved
midwave infrared (1800 - 6000 cm-1) spectra were collected at 100 Hz and 32 cm-1 resolution. A low
dimensional radiative transfer model was used to characterize plume emissions in terms of area, temperature, soot
emissivity, and species concentrations. Combustion emissions have ~100 ms duration, 1200 - 1600 K temperature, and
are dominated by H2O and CO2. Non-combusting plume emissions last ~20 ms, are 850 - 1050 K, and show significant
continuum (emissivity ~0.36) and CO structure. Munitions were discriminated with 92 - 96% classification accuracy
using only 1 - 3 firing signature features.
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