Paper
7 May 2012 Diode pumped alkali laser kinetics: comparison of theory and experiment
Charleton D. Lewis, David E. Weeks, Glen P. Perram
Author Affiliations +
Abstract
The performance of Diode Pumped Alkali Lasers (DPAL) depends critically on both collisionally broadened linehapes and rates for fine structure mixing. The first four potential surfaces for K, Rb, and Cs interactions with rare gases have been computed at the MCSCF/MR SOCI level. These surfaces are then used to compute scattering matrix elements for the spin-orbit relaxation, yielding temperature dependent cross-sections. Theoretical predictions are compared to recent experimental results. The observed fine structure mixing rates for rare gas collisions are interpreted in terms of collision adiabaticity. For molecular partners, ro-vibrational energy appears to dominate the mechanism.
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Charleton D. Lewis, David E. Weeks, and Glen P. Perram "Diode pumped alkali laser kinetics: comparison of theory and experiment", Proc. SPIE 8381, Laser Technology for Defense and Security VIII, 83810A (7 May 2012); https://doi.org/10.1117/12.920586
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KEYWORDS
Cesium

Rubidium

Chemical species

Diodes

Semiconductor lasers

Scattering

Laser applications

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