We have grown several high atomic number and high density ternary single crystals for variety of sensors. These materials are layered compounds (also designated as 2D) and have shown great promise for radiation and optical sensors. For achieving the good quality single crystals thermal characteristics are required, we have characterized thallium lead iodide, thallium mercury iodide and thallium gallium selenide synthesized from binary thallium and mercury and lead salts. Both thermal gravimetric and differential thermal analysis was performed from 50 to 9000C using two systems including a PerkinElmer Pyris 1 TGA and platinum sample pan in the nitrogen atmosphere. We will compare these data with available phase diagram for the grown stoichiometric compound.
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