Unprotected electronic components exposed to moisture from high humidity may fail due to corrosion of metal leads or
other unfavorable reactions on chemically sensitive components. This is of high interest for silicones that encapsulate
Light Emitting Diodes (LEDs) dies. For these applications, moisture and oxygen may react with materials, such as
phosphor, used to make white LEDs for back-lighting applications and decrease or change the light output and color
over time. Of the polymeric adhesives and sealants commercially available, silicones are used for their thermal stability,
clarity, and comparably low modulus that provides stress relief during thermal cycling. In addition, silicones are also
known to be very permeable to low molecular weight gases such as water vapor and oxygen. Recently, several types of
silicones were tested for the oxygen and water vapor transmission rates, and it was found that they can have drastically
different results. Silicone properties strongly affecting permeability are polymer backbone chemistry, crosslink density
and fillers. Phenyl (C6H5) and trifluoropropyl (CF3CH2) groups are used to optimize the refractive index of optically
clear silicones. The effect of chemical composition on the water vapor transfer rate (WVTR) and the oxygen transfer rate
(OTR) at 400 C and 90% Relative Humidity was investigated on several silicones with various refractive indices and
compared to polydimethylsiloxane (PDMS) with similar durometers. It was found that polymer backbone chemistry had
a significant influence on the permeation rates and will assist in material selection when designing for low-permeable
barriers to improve package reliability.
The improvement of silicone-based materials used in space and aerospace environments has garnered much attention for
several decades. Most recently, an Ultra Low Outgassing™ silicone incorporating innovative reinforcing and functional
fillers has shown that silicone elastomers with unique and specific properties can be developed to meet applications
requiring stringent outgassing requirements. This paper will report on the next crucial step in qualifying these materials
for spacecraft applications requiring chemical and physical stability in the presence of ionizing radiation. As a first step
in this process, selected materials were irradiated with Co-60 gamma-rays to simulate the total dose received in near-
Earth orbits. The paper will present pre-and post-irradiation response data of Ultra Low Outgassing silicone samples
exposed under ambient air environment coupled with measurements of collected volatile condensable material (CVCM)
and total mass loss (TML) per the standard conditions in ASTM E 595. The data will show an insignificant effect on the
CVCMs and TMLs after exposure to various dosages of gamma radiation. This data may favorably impact new
applications for these silicone materials for use as an improved sealant for space solar cell systems, space structures,
satellite systems and aerospace systems.
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