Ms. Svetlana Zapalova Profile

Svetlana Zapalova

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Proceedings Article | 25 May 2022 Poster + Paper

Transparent glass-ceramics based on Ti3+-doped ZnAl2O4 nanocrystals: synthesis, structure and optical properties

Kirill Eremeev, Olga Dymshits, Irina Alekseeva, Alexander Khubetsov, Marina Tsenter, Svetlana Zapalova, Liza Basyrova, Pavel Loiko, Alexander Zhilin

Proceedings Volume 12142, 121421G (2022) https://doi.org/10.1117/12.2624442

KEYWORDS: Glasses, Crystals, Aluminum, Titanium, Ions, Absorption, Raman spectroscopy, Nanocrystals, Zinc, Temperature metrology

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Trivalent titanium ions (Ti³⁺) are known for their broadband emission in the visible and near-IR. Zinc aluminate spinel, or gahnite (ZnAl₂O₄) is known as a host matrix for transition-metal ions. We report on the structure and spectroscopic properties of transparent zinc aluminosilicate glass-ceramics (GCs) nucleated by TiO2 and based on Ti³⁺-doped ZnAl₂O₄ nanocrystals. The initial glasses were melted under different redox conditions. After heat-treatments at the temperatures in the range of 720 to 1100 °C, transparent GCs were obtained. The materials were studied by the DSC method, XRD analysis, Raman, absorption and luminescence spectroscopy. The main crystalline phase in GCs is ZnAl₂O₄ with a cubic structure. The crystals are 5 - 21 nm in size. Their unit cell parameters vary with the heat-treatment temperature due to the titanium ions entering the gahnite nanocrystals. The volume fraction of gahnite nanophase increases with the heat treatment temperature. At 1000 – 1100 °C, TiO₂ (rutile) crystals with a size of 11 - 37 nm also appear. In GCs obtained from glasses melted under reducing conditions, broadband absorption is observed in the visible and near IR due to the Ti³⁺ ions in Oh positions in ZnAl₂O₄ crystals, the absorption of Ti³⁺ - Ti⁴⁺ pairs and the appearance of Ti³⁺ self-doped rutile. By changing the redox conditions of the glass synthesis, one can control the content of titanium ions in various oxidation states and the spectral properties of GCs.

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