We present results and analysis of 5 Gb/s On-Off-Keyed (OOK) data transmission at ~ 4.6-micron wavelength using, at room temperature, a directly modulated, single-mode DFB-QCL transmitter and a Resonant-Cavity Infrared Detector (RCID) receiver. The DFB-QCL design enables relatively high 165-mW CW output power. We used a 3-mm device with ~ 4-micron aperture for stable single-spatial-mode operation, operating at 65 mW. The RCID detector suppresses background radiation while providing enhanced quantum efficiency, ~ 60%, with low polarization dependence and low dark current at room temperature. The data transmission was achieved with no transmitter pulse shaping, consistent with lower-cost transceiver implementation.
Calcite is a birefringent material with optical anisotropy that becomes extreme in the infrared, allowing for the excitation of highly-directional, sub-diffractional hyperbolic modes. In this talk, I will discuss our recent work that focuses on understanding the optical behavior of hyperbolic modes supported within asymmetric nanostructures formed in calcite crystals with in-plane anisotropy, including our recent findings that demonstrate how the resonant frequency and directional power flow can be tuned by simply rotating gratings with respect to the crystal axes of calcite – without changing the shape of the gratings.
Resonant cavity infrared detectors (RCIDs) can reduce the noise in sensing a laser signal by strongly suppressing background photocurrent at wavelengths outside the narrow spectral band of interest. We recently reported an RCID with 100-nm-thick InAsSb/InAs absorber, GaAs/AlGaAs bottom mirror, and Ge/SiO2 top mirror. At T = 300 K, the external quantum efficiency reached 58% atλres ≈ 4.6 μm, with linewidth δλ = 27 nm. The characteristics at 125 K implied a specific detectivity of 5.5 × 1012 cm Hz½/W, which is more than 3× higher than for a state-of-the-art broadband HgCdTe device operating at that temperature. However, a prominent variation with mesa diameter of the deposited Ge spacer thickness made it difficult to predictably control λres for devices processed with a given diameter. This has been addressed by measuring the reflectivity spectrum following deposition of the spacer, so that thicknesses of the top mirror’s SiO2 and Ge layers could be adjusted appropriately to attain a targeted resonance. This was especially beneficial in matching the λres for a small mesa, needed to minimize the capacitance in high-frequency measurements, to the emission wavelength of a given ewquantum cascade laser.
For some applications, resonant cavity infrared detectors (RCIDs) offer advantages over traditional broadband photodetectors. The addition of a resonant cavity allows for higher external quantum efficiency (EQE), faster response time, and narrower spectral response for enhanced selectivity. Recently, the US Naval Research Laboratory demonstrated RCIDs with EQE of 34% and D∗ of 7 × 109 at room temperature, centered at 4.0 μm (46 nm FWHM). Princeton University has demonstrated that these RCIDs can detect gas-phase nitrous oxide (N2O) at room temperature with only a broadband light source and no other optical components. The results imply that a simple RCID-LED pair manufactured on a semiconductor wafer would provide a viable gas sensor. The manufacturing process could be completely automated, resulting in mass-producible optical gas sensors. Progress has been made for developing RCIDs at other wavelengths. Based on the achieved detection limit of 4% N2O at 4.0 μm, with 3 cm path length, leak detection of percentage-level concentrations of gases is definitely viable. The potential for operating at a more optimal wavelength to attain high-precision measurements at part-per-million (ppm) levels is still under investigation.
Frequency combs based on mid-infrared cascade lasers have been studied both experimentally and theoretically in recent years. So far only FM combs with quasi-cw output have been reported for interband cascade lasers (ICLs). We discuss the parameters that need to be achieved to realize passive mode locking in ICLs. The results are obtained from a comprehensive numerical model based on the wavevector-resolved Bloch equations coupled to the one-dimensional wave equation. We find that the design of the saturable absorber, in particular the carrier extraction time and length, is very important, while passive mode locking should already be achievable for the experimentally demonstrated values of group velocity dispersion. The leakage into the high-index GaSb substrate should also be controlled via the waveguide design.
There is a general need to detect and measure the concentration of multiple hydrocarbon species in a gas. In this work, we have developed a tunable external cavity interband cascade laser (EC-ICL) that covers the wavelength range λ = 3216 to 3479 nm (Δ λ = 263 nm) in continuous wave (CW) mode. The EC-ICL provides a versatile broadband source for hydrocarbon detection and measurements. To demonstrate this capability, we incorporated the EC-ICL into an absorption spectroscopy sensor that includes a detector, data acquisition electronics, and software for data processing and spectral fitting. The AR/HR-coated laser with 3 mm cavity length is mounted epi-up on a heat spreader with a TEC. The external cavity is formed by a ruled diffraction grating in a Littman-Metcalf configuration to achieve broad tuning. The wavelength is tunable across the entire range with speed exceeding 15 Hz and effective system spectral resolution of approximately Δν = 0.7 cm-1 in a broad tuning mode. In addition, we developed and demonstrated mode-hop-free (MHF) tuning capability of the system for up to 0.4 cm-1 tuning range around an arbitrary user selected central wavelength with estimated spectral resolution significantly lower than Δν = 0.01 cm-1. Using the EC-ICL, we demonstrated direct absorption measurements of mixtures of methane, ethane, and propane inside an absorption cell. Furthermore, we demonstrated high resolution MHF measurements for methane in a low pressure fiber gas cell. The EC-ICL technology demonstrated in this work is appropriate for a variety of tunable laser applications spanning λ = 3 – 6 μm.
Molecular vibrations can couple to optical cavities to create new hybrid states called polaritons. The magnitude of this coupling, measured as the vacuum Rabi splitting (Ω), correlates with modified materials processes such as photon emission, molecular energy transfer, and chemical reaction rates. In this talk, I will first discuss active control of cavity coupling strength. We demonstrate active tuning of excitonic strong coupling in a system where organic dyes strongly couple to propagating surface plasmon polaritons (SPPs) and modulation of vibrational strong coupling in a Fabry-Perot cavity coupled to an organic charge shuttling molecule. Next, I will discuss results indicating modified chemical reaction rates for an alcoholysis addition reaction forming urethane monomers. Cavity tuning was used to selectively couple to reactant, solvent, and product vibrational modes resulting in a chemical response that is cavity tuning dependent. Lastly, and in light of the search for an understanding of the mechanisms leading to modified chemical and physical properties, I will present a theoretical description of the density of polariton states relative to molecular dark states. This work will also discuss the differences between polariton states generated in microcavities, slabs, and in the bulk.
Mid-IR emitters grown on silicon will be simpler to process and less expensive to manufacture than devices grown on GaSb. Here we report interband cascade light emitting devices grown on 4° offcut silicon. While core heating limited cw emission from epi-up devices on GaSb, dissipation via the substrate allowed devices on silicon to operate to much higher currents. Accounting for differences in architecture, the efficiency was approximately 75% of that for the best previous epi-down ICLEDs grown on GaSb. At 100 mA, 200-µm-diameter mesas produced 184 µW cw at T = 25 °C and 140 µW at 85 °C.
Mid-infrared, interband-cascade, light-emitting devices (ICLEDs) have the potential to improve the performance of trace-gas sensors for air quality and greenhouse gas measurements. ICLEDs are broadband, incoherent, high-optical-power devices (up to ~5 mW continuous-wave at room temperature). We present an ICLED-based, methane sensor using a hollow-core fiber and direct absorption spectroscopy. A 1σ noise equivalent absorption of 0.17 ppmv CH4 at 1 Hz was achieved (1.13e-5 absorbance). Sub-ppmv methane detection is relevant for monitoring emissions near sources such as petrochemical infrastructure, agricultural activities, and wastewater treatment plants.
Mid-infrared semiconductor lasers have emerged as indispensable compact coherent sources for military and commercial applications. While much of the historical emphasis has been on maximizing the output power and/or spectral purity, a recent new focus has been on engineering these lasers to operate as optical frequency combs (OFCs) for broadband real-time spectroscopy. In particular, the combination of low-drive-power and broad gain bandwidth has made interband cascade laser (ICL) OFCs an attractive complement to quantum cascade laser OFCs operating at longer wavelengths. Moreover, ICL combs can potentially be incorporated into fully-integrated dual-comb spectrometers that employ fast, room-temperature IC photodetectors processed on the same chip. However, the high refractive index of the ICL’s GaSb substrate poses some challenges to the optical waveguiding. Because the modal index is considerably lower than that of the substrate, the optical field can penetrate the bottom cladding layer and leak into the GaSb, inducing wavelength-dependent interference that modifies the gain and group velocity dispersion (GVD) profiles. Even when the effect on lasing threshold is small, the comb properties can be adversely affected. Using the sub-threshold Fourier transform technique, we studied ICL combs with various ridge widths, substrate thicknesses, and center wavelengths. This allowed us to evaluate the effects of modal leakage on the GVD. We find that the resonant nature of the substrate modes induces oscillations, which affect both the spectral bandwidth and the phase-locking properties above threshold. Strategies to mitigate the GVD’s undesired and unpredictable spectral variation will be presented.
The mid-infrared spectra of many polar materials are dominated by highly reflective reststrahlen bands that occur between the transverse and longitudinal optical phonons. Within the reststrahlen bands, light can couple with optical phonons to support phonon-polariton modes. These modes enhance light-matter interactions through the concentration of light to nanoscale dimensions, and therefore, are particularly promising for mid-infrared nanophotonic applications. Here, we discuss our work on expanding the spectral range over which phonon-polaritons are supported by using new material systems, as well as active tuning of the modes via carrier photoinjection. In particular, we report on the confinement of hyperbolic phonon-polaritons in calcite, a ubiquitous polar material. We also report the use of the LO-phonon-plasmon-coupling (LOPC) effect to actively tune the Berreman mode of a GaN thin film.
By exploiting the bi-functional operation capability of interband cascade laser (ICL) frequency combs, we have utilized the laser medium not only for comb generation, but also as a room-temperature photodetector with near-GHz bandwidth for multi-heterodyne beating of the comb lines. Our self-contained platform consuming less than 2 W of electrical power enables free-running room-temperature broadband dual-comb spectroscopy of 1,1 difluoroethane with ~3% standard deviation in 2 ms over 600 GHz of optical bandwidth around 3.6 µm. We will discuss progress toward the optimization of ICL combs for realizing compact, low-power chemical sensors operating in the MWIR.
Interband cascade laser (ICL) optical frequency combs are promising midwave infrared sources for dual comb spectroscopy probing the strong fundamental absorption lines of numerous chemical and biological agents. In this work, a 4-mm-long ICL frequency comb emitting at 3.3 μm was operated by single-cavity optical self-injection. The experiments employing a free-space optical self-injection length of 1.1m with fine-delay control demonstrated a tuning range of 119MHz around the free-running intermode beat frequency of 9.58 GHz. For resonant fine-delay the line width of the intermode beat frequency was reduced to 390 kHz, what is an improvement by a factor of 40 in comparison to the solitary laser line width.
We report a preliminary investigation of ion bombardment (IB) effects on interband cascade laser (ICL) properties. Under some conditions, IB almost completely suppresses the vertical transport through a broad-area laser, although other times only a partial or negligible suppression is observed. To elucidate the mechanism that induces the suppression and in what part of the structure it occurs, we investigated the effects of IB on samples containing only ICL sub-regions. While IB increased the resistivity of a lightly-n-doped GaSb layer such as that used as a top or bottom separate confinement layer in an ICL, that layer was still much too conductive to strongly suppress the current flowing through a full device. The voltage drop was larger following IB of an InAs-AlSb superlattice such as that used in the top and bottom optical cladding layers in an ICL, although the effect was not large enough to fully account for the strong net suppression. And finally, the resistivity of an interband cascade LED containing the same active stages as an ICL was actually found to decrease following IB. Despite the inconclusive and sometime inconsistent findings of this study, it is nonetheless clear that if the effects can be controlled reproducibly, IB may provide a valuable tool for enhancing such ICL device configurations as weakly-index-guided narrow ridges and interband cascade vertical-cavity surface-emitting laser mesas that inject current and emit light only within a small central aperture.
Jill Nolde, Eric Jackson, Mijin Kim, Chul Soo Kim, Chadwick Canedy, Michael Warren, Stephanie Tomasulo, Chaffra Affouda, Erin Cleveland, Igor Vurgaftman, Jerry Meyer, Edward Aifer
For diffusion-limited nBn detectors, using an absorption layer much thinner than the optical attenuation length and minority carrier diffusion length can improve the dark current to provide greater sensitivity or higher temperature operation. However, if the quantum efficiency (QE) also decreases with absorber thickness, the advantage of reduced dark current is eliminated. We discuss the use of a metallic grating to couple the incident light into laterally propagating surface plasmon polariton (SPP) modes and increase the effective absorption length. We fabricate the gratings using a deposited Ge layer, which provides a uniform profile without increasing the dark current. Using this process in conjunction with a 0.5-μm-thick InAsSb absorber lattice-matched to GaSb, we demonstrate an external QE of 34% for T = 78 to 240 K. An nBn structure with an InAs0.8Sb0.2 absorber that is grown metamorphically on GaSb using a step-graded InGaSb buffer has a peak external QE of 39% at 100 K, which decreases to 32% by 240 K. Finally, we demonstrate that a grating with SPP resonance near the bandgap extends the absorption band and can potentially reduce the dark current by another factor of 3 to 8 times in addition to the 5 × reduction due to the thinner absorber.
Optical frequency combs have revolutionized the field of high resolution real-time molecular spectroscopy. Here, we demonstrate an electrically-driven optical frequency comb whose sub-picosecond pulses span more than 1 THz of spectral bandwidth centered near 3.3 mm. This is achieved by passively mode locking an interband cascade laser in a multi-contact architecture with gain and saturable absorber sections monolithically integrated on the same chip.
The high optical losses of metal-based plasmonic materials have driven an extensive search for alternative lower-loss materials that can support plasmonic-like effects, such as sub-diffraction confinement of optical fields. One such alternative employs phonon-mediated collective-charge oscillations (surface phonon polaritons, SPhPs) that can be optically excited in nanostructured polar dielectric materials. Similar to plasmonics, tailoring the geometry of polar-dielectric resonators results in resonances that can be spectrally tuned throughout the spectral range between the LO and TO phonons. However, generally, the spectral position and amplitude of these resonances remain fixed after sample fabrication. In this presentation, we discuss recent advancements made by our group in achieving actively tunable localized SPhP resonances in the long-wave- and far-infrared spectral regimes. In particular, we focus on three experiments that demonstrate active modulation of resonances. The first and second experiments focus on tuning the spectral position of localized SPhP resonances in cylindrical nanopillars that are etched into indium phosphide and silicon carbide substrates. In both of these cases we are able to induce resonance shifts as large as 15 cm-1 by optically injecting free-carriers into the pillars. The optical injection introduces a reversible, free-carrier perturbation to the dielectric permittivity that results in a spectral shift of the resonances. While the effects investigated for both the InP and SiC systems are similar, each material allows us to explore a different aspect of the phenomena. For InP we investigate the effects in the far-infrared (303-344 cm-1) with steady-state carrier photoinjection, while for SiC we investigate the dynamics of frequency modulated resonances in the long-wave infrared (797-972 cm-1) via transient reflection spectroscopy. Lastly, in the third experiment we demonstrate the ability to modulate the amplitude of resonances by coating SiC nanopillars with vanadium dioxide, a well-known phase change material that undergoes a metal-to-insulator transition near a temperature of 70 C. As such, we show that by exploiting this phase change we are able to modulate the reflectance and thermal emission of nanopillar arrays. The results described in this work may open the door to tunable, narrow-band thermal sources that operate in the long-wave to far-infrared spectral regimes.
We report resonant-cavity infrared detectors with absorbers that consist of only five quantum wells, but exhibiting 34% external quantum efficiency at room temperature at the resonant wavelength of 4.0 μm. The FWHM linewidth is 46 nm, and the peak absorption is enhanced by nearly a factor of 30 over that for a single pass through the absorber. Although the Shockley-Read lifetime in the current material is much shorter than the state of the art, the dark current density is at the level of HgCdTe detectors as quantified by “Rule 07”. The Johnson-noise limited detectivity (D*) at 21°C is 7 × 109 cm Hz½/W. We expect that future improvements in the device design and material quality will lead to higher quantum efficiency, as well as a significant reduction of the dark current density consistent with the very thin absorber.
In order to accurately characterize the photoluminescence from an InAs/AlAsSb multi-quantum well hot carrier absorber, the band structure is generated with an 8 band k·p model utilizing the Naval Research Laboratory’s MultiBands® software tool. The simulated spectra for transitions between the lowest energy electron sub-band and the four lowest hole sub-bands are computed from the optical matrix elements and the calculated band structure. In depth temperature dependent simulations for absorption and photogenerated recombination of electron-hole carriers are compared with the experimental spectra. There is close agreement between simulated and observed spectra in particular, the room temperature e1-hh1 simulated transition energy of 805 meV nearly matches the 798 meV transition energy of the experimental photoluminescence spectra. Also, the expected energy separations between local maxima (p1-p2) in the simulated/experimental spectra have a difference of just 2 meV. The model has a valence band offset of 63 meV which is in general agreement with photoluminescence feature that suggests a valence band offset of 70 meV.
To analyze the ‘hot’ carriers, the photoluminescence spectra is evaluated with three different methods, a linear fit to the high energy portion of the spectra and two methods which utilize either an equilibrium or non-equilibrium generalized Planck relation to fit the whole spectrum. The non-equilibrium fit enables individual carrier temperatures for both holes and electrons. This results in two very different carrier temperatures for holes and electrons: where the hole temperature, Th, is nearly equal to the lattice temperature, TL; while, the electron temperature, Te, is ‘hot’.
We have experimentally investigated the effects of sidewall corrugations on the beam quality and brightness of narrow-ridge interband cascade lasers (ICLs) emitting at λ ≈ 3.3 μm. We find that at this wavelength a corrugation period of 10 µm provides greater suppression of higher-order lateral modes than a shorter period of 2-4 µm. While the power and efficiency decrease modestly for the longer corrugation period, there is a net increase of the brightness defined as the output power divided by the beam quality factor M2 . However, the brightness degrades when the corrugation amplitude is increased from 2 µm to 3.5 µm, since lower output power offsets a relatively small improvement of the beam quality
For diffusion limited nBn detectors, using an absorption layer much thinner than the optical attenuation length and minority carrier diffusion length can improve the dark current. As the absorber thickness decreases, the lower dark current increases the signal-to-noise ratio to provide greater sensitivity or higher temperature operation. However, if the quantum efficiency (QE) also decreases with absorber thickness, the advantage of reduced dark current is eliminated. Here we discuss the use of a metallic grating to couple the incident light into laterally-propagating surface plasmon polariton (SPP) modes, so as to increase the effective absorption length. We fabricate the gratings using a deposited Ge layer, which provides a uniform grating profile without increasing the dark current. Using this process in conjunction with a 0.5 μm-thick InAsSb absorber lattice-matched to GaSb, we demonstrate an external QE of 34% for T = 78–240 K. An nBn structure with an InAs0.8Sb0.2 absorber that is grown metamorphically on GaSb using a step-graded InGaSb buffer has a peak external QE of 39% at 100 K, which decreases to 32% by 240 K. Finally, we demonstrate that a grating with SPP resonance near the bandgap extends the absorption band, and can potentially reduce the dark current by a factor of 3–8 in addition to the 5× reduction due to the thinner absorber.
Integrated mid-infrared frequency combs promise to revolutionize chemical sensing. A technologically important approach is to employ a III-V semiconductor in a microresonator-based nonlinear comb. For a comb centered on 4.5 μm, a suitable waveguide material is InGaAs on InP. However, this approach also introduces pronounced higher-order group velocity dispersion that can make it difficult to achieve stable broadband output. One way to stabilize multiple solitons and the repetition rate is to pump simultaneously at two wavelengths separated by one or a few free spectral ranges of the microresonator. Here we show theoretically that this pumping scheme can lead to stable soliton crystals and calculate the required ranges of pump powers and wavelengths. We also show that this stabilization effect occurs only over a limited range of pump power and detuning parameters. For example, for the large detunings needed to isolate soliton pulses, the relative pump power is constrained to rcr⪅P2/P1⪅Rcr with rcr≈40% and Rcr≈97%. The stable parameter ranges are similar for third-order, sixth-order, and all-order dispersion.
Conventional optical components are limited to size-scales much larger than the wavelength of light, as changes to the amplitude, phase and polarization of the electromagnetic fields are accrued gradually along an optical path. However, advances in nanophotonics have produced ultrathin, so-called “flat” optical components that beget abrupt changes in these properties over distances significantly shorter than the free space wavelength. While high optical losses still plague many approaches, phonon polariton materials have demonstrated long lifetimes for localized modes in comparison to plasmon-polariton based nanophotonics. Our work predicts a further 14-fold increase in the optic phonon lifetime and we experimentally report a ~3-fold improvement through isotopic enrichment of hexagonal boron nitride (hBN). We establish commensurate increases in the phonon polariton propagation length via direct imaging of polaritonic standing waves by means of infrared nano-optics. Our results provide the foundation for a materials-growth-directed approach towards realizing the loss control necessary for the development of phonon polariton based nanophotonic devices.
We are developing midwave infrared (mid-IR) quantum cascade lasers (QCLs) and interband cascade lasers (ICLs) bonded to silicon. The heterogeneous integration of mid-IR photonic devices with silicon promises to enable low-cost, compact sensing and detection capabilities that are compatible with existing silicon photonic and electronic technologies. The first Fabry-Perot QCLs on silicon were bonded to pre-patterned silicon-on-nitride-on-insulator (SONOI) substrates. Lateral tapers in the III-V mesas transferred the optical mode from the hybrid III-V/Si active region into the passive silicon waveguides, with feedback provided by reflections from both the III-V tapers and the polished passive silicon facets. Lasing was observed at 4.8 m with threshold current densities as low as 1.6 kA/cm2 when operated in pulsed mode at T = 20 ºC. The first mid-IR DFB lasers integrated on silicon employed gratings patterned into the silicon waveguides before bonding. Over 200 mW of pulsed power was generated at room temperature, and operated to 100 °C with T0 = 199 K. Threshold current densities were measured below 1 kA/cm2.The grating imposed considerable wavelength selectivity and 22 nm of thermal tuning, even though the emission was not spectrally pure. Ongoing research focuses on flip-chip bonding to improve heat sinking for continuous-wave operation, and arrayed waveguide gratings for beam combining. ICLs have also been bonded to silicon and the GaSb substrate has been chemically removed with an InAsSb etch-stop layer. Tapered ICL ridges designed for lasing in a hybrid III-V/Si mode have been processed above passive silicon waveguides patterned on SOI. A goal is to combine the power generated by arrays of QCLs and ICLs residing on the same chip into a single, high-quality output beam.
We report interband cascade light-emitting devices (ICLEDs) emitting at λ ≈ 3.1mm, which produce generate higher radiance, output power, and efficiency than any other mid-infrared LEDs operating in continuous wave (cw) mode near and above room temperature. This is achieved in part by splitting the 22 LED stages into four groups placed at the antinodes of the near-normal optical field when the device is mounted epitaxial-side-down on a reflective metal contact. At an applied bias of 9.4 V and injection current of 0.6 A, an ICLED with mesa diameter 400 mm produces 2.9 mW of cw output power at T = 25°C, which corresponds to a radiance of 0.73 W/cm2/sr. The wall-plug efficiency ranges from 0.4% at low powers to 0.05% at the maximum output power.
We will focus on approaches which make use of light-matter interactions to alter the chemical behavior of a target molecular species. This is done through cavity coupling to a molecular vibration. Coupling vibrational transitions to resonant optical modes creates vibrational polaritons shifted from the uncoupled molecular resonances and provides a convenient way to modify the energetics of molecular vibrations. This approach is a viable method to explore controlling chemical reactivity and energy relaxation. Here, we demonstrate frequency domain results for vibrational bands strongly coupled to optical cavities. We experimentally and numerically describe strong coupling between a Fabry-Pérot cavity and several molecular species (e.g., poly-methylmethacrylate, thiocyanate, hexamethyl diisocyanate). We investigate strong and weak coupling regimes through examination of cavities loaded with varying concentrations of a urethane monomer. Rabi splittings are in excellent agreement with an analytical description using no fitting parameters. We show that coupling strength is a function of molecule/cavity mode overlap by systematically altering the position of a molecular slab throughout a first order cavity with results agreeing well with analytical and transfer matrix predictions. Further, remote molecule-molecule interaction will be explored by placing discrete and separated molecular layers throughout a cavity. In addition to establishing that coupling to an optical cavity modifies the energy levels accessible to the coupled molecules, this work points out the possibility of systematic and predictive modification of the excited-state kinetics of vibration-cavity polariton systems. Opening the field of polaritonic coupling to vibrational species promises to be a rich arena amenable to a wide variety of infrared-active bonds that can be studied in steady state and dynamically.
The effects of gamma radiation on Fabry–Perot interband cascade lasers (ICLs) were investigated. Two ICLs were exposed to cobalt-60 gamma rays for a total dose of 500 krad(Si) each. The ICLs do not show any evidence of changes in performance, including output power, threshold current, slope efficiency, or spectral frequency. These results demonstrate that ICLs are insensitive to gamma irradiation up to exposure rates above those normally encountered within a shielded spacecraft.
KEYWORDS: Spectroscopy, Signal to noise ratio, Quantum cascade lasers, Absorption, Methane, Spectral resolution, Optical engineering, Signal detection, Digital filtering, Sensors
While midinfrared radiation can be used to identify and quantify numerous chemical species, contemporary broadband midinfrared spectroscopic systems are often hindered by large footprints, moving parts, and high power consumption. In this work, we demonstrate multiheterodyne spectroscopy (MHS) using interband cascade lasers, which combines broadband spectral coverage with high spectral resolution and energy-efficient operation. The lasers generate up to 30 mW of continuous-wave optical power while consuming <0.5 W of electrical power. A computational phase and timing correction algorithm is used to obtain kHz linewidths of the multiheterodyne beat notes and up to 30 dB improvement in signal-to-noise ratio. The versatility of the multiheterodyne technique is demonstrated by performing both rapidly swept absorption and dispersion spectroscopic assessments of low-pressure ethylene (C2H4) acquired by extracting a single beat note from the multiheterodyne signal, as well as broadband MHS of methane (CH4) acquired with all available beat notes with microsecond temporal resolution and an instantaneous optical bandwidth of ∼240 GHz. The technology shows excellent potential for portable and high-resolution solid-state spectroscopic chemical sensors operating in the midinfrared.
We report interband cascade light-emitting devices (ICLEDs) emitting at peak wavelengths of 3.1 to 3.2 μm that display higher maximum output powers, radiances, and efficiencies than any earlier midwave-infrared LEDs when operated at 10 to 105°C. To enhance the output power, we split the ICLED’s 22 active stages into four groups positioned at antinodes of the optical field so that the emission interferes constructively when reflected at near-normal incidence from the metal contact of the epitaxial-side-down mounted device. At an applied bias of 9.6 V and injection current of 0.6 A, an ICLED with mesa diameter of 400 μm produces 3.1 mW of continuous-wave output power at T=10°C, which corresponds to a radiance of 0.79 W/cm2/sr. The same device generates 1.7 mW at T=105°C.
Interband cascade lasers (ICLs) are a promising light source for the mid-infrared (mid-IR) spectral range. However, for certain applications such as spectroscopic techniques for chemical sensing and non-invasive disease diagnostics, a broadband incoherent radiation source such as an LED may be more desirable. Here we investigate both ICLs and interband cascade light emitting devices (ICLEDs). The ICLEDs follow the example of ICLs by cascading multiple active stages in series to improve efficiency and increase output power, but without an optical cavity to provide feedback.
In this work we will present studies of these devices using high hydrostatic pressure techniques to determine the key efficiency limiting processes so that they might be mitigated. The application of hydrostatic pressure causes reversible changes to the band structure, increasing the energy of the conduction band gamma point and moving other key points in the band structure. This makes it a useful technique to probe recombination processes that depend on band gap and offsets, independently of temperature. For a laser dominated by CHCC Auger recombination, as is typical in narrow band gap devices for the mid-IR, one would expect a decrease in threshold current with increasing pressure, as the Auger process decreases with increasing band gap. However, the lasers studied here exhibit an increase in threshold current with pressure, indicating that other processes also play a significant role. We will discuss the relative contributions from Auger recombination and other processes such as defect-related recombination and carrier leakage in these devices, with respect to relevant modelling.
Silicon integration of mid-infrared (MIR) photonic devices promises to enable low-cost, compact sensing and detection capabilities that are compatible with existing silicon photonic and silicon electronic technologies. Heterogeneous integration by bonding III-V wafers to silicon waveguides has been employed previously to build integrated diode lasers for wavelengths from 1310 to 2010 nm. Recently, Fabry-Perot Quantum Cascade Lasers integrated on silicon provided a 4800 nm light source for MIR silicon photonic applications. Distributed feedback (DFB) lasers are appealing for many high-sensitivity chemical spectroscopic sensing applications that require a single frequency, narrow-linewidth MIR source. While heterogeneously integrated 1550 nm DFB lasers have been demonstrated by introducing a shallow surface grating on a silicon waveguide within the active region, no mid-infrared DFB laser on silicon had previously been reported. Here we demonstrate quantum cascade DFB lasers heterogeneously integrated with silicon-on-nitride-oninsulator (SONOI) waveguides. These lasers emit over 200 mW of pulsed power at room temperature and operate up to 100 °C. Although the output is not single mode, the DFB grating nonetheless imposes wavelength selectivity with 22 nm of thermal tuning.
Interband cascade lasers (ICLs) have proven to be efficient semiconductor sources of coherent mid -infrared (mid-IR) radiation. Single mode distributed-feedback (DFB) ICLs are excellent high-resolution spectroscopic sources for targeting important molecular species in the mid-IR fingerprint region, but are limited to a narrow spectral tuning range. Recent developments in multi-heterodyne spectroscopy with multi-mode Fabry-Perot (FP) lasers have enabled significant progress towards broadband high-resolution spectroscopic sensing applications in the mid-infrared. Here, we characterize the mode structure and tuning properties of multi-mode FP-ICLs for the purpose of evaluating the feasibility of ICL-based multiheterodyne spectroscopy.
While much of the previous work on interband cascade lasers (ICLs) has been limited to the 3-4 μm spectral range, it was recently demonstrated at NRL and elsewhere that the low threshold current and power densities characteristic of ICLs can be extended to longer wavelengths. Here we report on the performance of ICLs operating in the 4.6-6.1 μm spectral range. The pulsed threshold current density at room temperature for an ICL emitting at λ = 4.8 μm is 220 A/cm2, the lowest ever reported for a semiconductor laser at such a long emission wavelength. Broad-area devices emitting in the 4.6-4.9 μm range are observed to maintain pulsed external differential quantum efficiencies (EDQEs) of 11-17% when operating at 375 K. An ICL emitting at λ = 5.7 μm exhibits a threshold current density of 450 A/cm2 and EDQE of 27% at room temperature. The Auger coefficients extracted from these thresholds indicate a systematic increase with wavelength, with the value at 6 μm being 3-4 times higher than that at λ = 3.5 μm.
Spontaneous parametric downconversion (SPDC) using periodically poled nonlinear optical crystals under the quasiphase- matching condition has found wide use in quantum optics. High efficiencies and good coupling to single-mode fibers resulted from using channel waveguides in crystals. It is often desirable to have a very narrow bandwidth for the signal and idler photons, but under the typical operating conditions, phase matching dictates the bandwidth of the SPDC to be of the order of <1 nm. This occurs because the co-propagating signal and idler photons are entangled, and an increase of the signal wave-vector is compensated by a decrease of the idler wave-vector. One way to reduce the bandwidth is by forming either external or internal cavities. Additionally, bandwidth reduction is possible without cavities when the signal and idler are counter-propagating, and the changes in the wave-vector with frequency are additive. To accomplish this a domain inversion on the wavelength scale is required. In this work, we experimentally demonstrate SPDC in one-dimensional KTP-based waveguides with sub-micron poling for forward and backward interactions. Some of the spectral features of the generated light are accounted for by mode coupling theory in periodically poled waveguides but other features are as yet not explained.
We report the single-mode operation of mid-infrared distributed-feedback (DFB) interband cascade lasers (ICLs) with contacts that cover only a fraction of the top surface of the laser ridge. This reduces the optical loss from the metal for the GaSb-relevant device configuration in which the grating is fabricated in the top layer of the DFB laser. Continuous wave (cw) room-temperature operation in a single spectral mode is observed for contact duty cycles as small as 14% when the width of the contact is fixed at 10 μm. The reduced contact duty cycle results in a factor of 2 decrease in the threshold current. The highest slope efficiency is observed for a contact duty cycle of 33%, for which the cw single-mode output power is as high as 6.8 mW.
Gallium nitride’s (GaN) material properties of broadband transparency, high thermal conductivity, and wide-band gap make it a promising candidate for high-power frequency conversion devices. The strong internal polarization of GaN leads to large second-order nonlinearity, but conventional phase matching is prevented due to weak birefringence. To obtain efficient nonlinear optic frequency conversion, patterned inversion growth has been developed to induce quasiphase matching (QPM). We have fabricated and tested periodically oriented GaN (PO-GaN) devices to obtain QPM frequency conversion. This report discusses our recent measurements of second harmonic generation resonances for these devices.
We report cw wallplug efficiencies (WPEs) for mid-infrared interband cascade lasers (ICLs) that are comparable to those of state-of-the-art quantum cascade lasers at temperatures ranging from the cryogenic regime to room temperature. The continuous wave (cw) WPE for 10-stage broad-area devices remains above 40% for temperatures up to 125 K, and is still <30% at T = 175 K. At 80 K the threshold current density for a 2-mm-long cavity is only 11 A/cm2, and slope efficiencies are < 2.2 W/A at all temperatures ≤ 200 K. A 32-μm-wide × 3-mm-long ridge with 7 active stages and high-reflection and anti-reflection coatings on the two facets displays a cw WPE of 24% at T = 200 K and 12% at T = 300 K. The cw WPE of another narrow-ridge ICL was 18% at room temperature.
The field of nanophotonics is based on the ability to confine light to sub-diffractional dimensions. Up until recently, research in this field has been primarily focused on the use of plasmonic metals. However, the high optical losses inherent in such metal-based surface plasmon materials has led to an ever-expanding effort to identify, low-loss alternative materials capable of supporting sub-diffractional confinement. One highly promising alternative are polar dielectric crystals whereby sub-diffraction confinement of light can be achieved through the stimulation of surface phonon polaritons within an all-dielectric, and thus low loss material system. Both SiC and hexagonal BN are two exemplary SPhP systems, which along with a whole host of alternative materials promise to transform nanophotonics and metamaterials in the mid-IR to THz spectral range. In addition to the lower losses, these materials offer novel opportunities not available with traditional plasmonics, for instance hyperbolic optical behavior in natural materials such as hBN, enabling super-resolution imaging without the need for complex fabrication. This talk will provide an overview of the SPhP phenomenon, a discussion of what makes a ‘good’ SPhP material and recent results from SiC and the naturally hyperbolic material, hBN from our research group.
Theoretical work has identified a new type of hybrid nanoresonator akin to a loaded-gap antenna, wherein the gap between two collinearly aligned metal nanorods is filled with active dielectric material. The gap optical load has a profound impact on resonances supported by such a “nanogap” antenna, and thus provides opportunity for (i) active modulation of the antenna resonance and (ii) delivery of substantial energy to the gap material. To this end, we have (i) used a bottom-up technique to fabricate nanogap antennas (Au/CdS/Au); (ii) characterized the optical modes of individual antennas with polarization- and wavevector-controlled dark-field microscopy; (iii) mapped the spatial profiles of the dominant modes with electron energy loss spectroscopy and imaging; and (iv) utilized full-wave finite-difference time-domain simulations to reveal the nanoscopic origin of the radiating modes supported on such nanogap antennas.
In addition to conventional transverse and longitudinal resonances, these loaded nanogap antennas support a unique symmetry-forbidden gap-localized transverse mode arising from the splitting of degenerate transverse modes located on the two gap faces. This previously unobserved mode is strong (E2 enhanced ~20), tightly localized in the nanoscopic (~30 nm separation) gap region, and is shown to red-shift with decreased gap size and increased gap dielectric constant. In fact, the mode is highly suppressed in air-gapped structures which may explain its absence from the literature to date. Understanding the complex modal structure supported on hybrid nanosystems is necessary to enable the multi-functional components many seek.
We report corrugated narrow-ridge interband cascade lasers emitting at λ ≈ 3.5 mm that have been fabricated using
CH4/Cl2- and BCl3-based inductively coupled plasma reactive ion etch processes, with largely similar results from
both types of etches. The highest brightness figure of merit was obtained at intermediate ridge width (28 mm), for
which the maximum cw output power at T = 25 °C was 522 mW and the corresponding wallplug efficiency and
beam quality factor were 10.3% and M2= 3.1, respectively. The high output power may be attributed to a 7-stage
design that employs thicker separate confinement layers for lower internal loss.
KEYWORDS: Signal detection, Sensors, Photons, Single photon, Correlation function, Single photon detectors, Beam splitters, Quantum optics, Signal generators, Solids
Low-photon-number sources can exhibit non-classical, counterintuitive behavior that can be exploited in the developing
field of quantum technology. Single photons play a special role in this arena since they represent the ultimate lowphoton-
number source. They are considered an important element in various applications such as quantum key
distribution, optical quantum information processing, quantum computing, intensity measurement standards, and others
yet to be discovered in this developing field. True deterministic sources of single photons on demand are currently an
area of intensive research, but have not been demonstrated in a practical setting. As a result, researchers commonly
default to the well-established workhorse: spontaneous parametric down-conversion generating entangled signal-idler
pairs. Since this source is thermal-statistical in nature, it is common to use a detected idler photon to herald the
production of a signal photon. The need exists to determine the quality of the single photons generated in the heralded
signal beam. Quite often, the literature reports a "heralded second-order coherence function" of the signal photons
conditioned on the idler photons using readily available single-photon detectors. In this work, we examine the
applicability of this technique to single-photon characterization and the consequences of the fact that the most commonly
used single-photon detectors are not photon-number resolving. Our results show that this method using non-photonresolving
detectors can only be used to characterize the signal-idler correlations rather than the nature of the signalphoton
state alone.
The high conversion efficiencies demonstrated by multi-junction solar cells over the past three decades have made them indispensable for use in space and are very attractive for terrestrial concentrator applications. The multi-junction technology consistently displays efficiency values in excess of 30%, with record highs of 37.8% under 1 sun conditions and over 44% under concentration. However, as material quality in current III-V multi-junction technology reaches practical limits, more sophisticated structures will be required to further improve on these efficiency values. In a collaborative effort amongst several institutions we have developed a novel multi-junction solar cell design that has the potential to reach the 50% conversion efficiency value. Our design consists of a three junction cell grown on InP substrates which achieves the optimal bandgaps for solar energy conversion using lattice matched materials. In this work, we present the progress in the different subcells comprising this multi-junction structure. For the top cell, InAlAsSb quaternary material is studied. For the middle, InGaAlAs and InGaAsP materials and devices are considered and for the bottom, a multi-quantum well structure lattice matched to InP for fine bandgap tunability for placement in an InGaAs cell is demonstrated.
We report a narrow-ridge interband cascade laser emitting at λ ≈ 3.5 μm that produces up to 592 mW of cw power
with a wallplug efficiency of 10.1% and beam quality factor of M2 = 3.7 at T = 25 °C. Furthermore, devices from a
large number of wafers with similar 7-stage designs and wavelengths spanning 2.8-4.7 μm exhibit consistently
higher pulsed external differential quantum efficiencies than earlier state-of-the-art ICLs.
We discuss approaches to increasing the cw output power of the interband cascade lasers (ICLs) for the midwave
infrared spectral region. While most of the attention to date has been focused on reducing the operating power of the
ICL, the optimization for maximum output power proceeds in a different direction. We find that increasing the
number of stage is beneficial, in that it boosts the slope efficiency with only a modest penalty due to higher
threshold power density and extra heating. The critical figure of merit for realizing high-power ICLs is the internal
loss, which can be estimated from the external differential quantum efficiency (EDQE) per stage. The internal loss
can be controlled by varying the thickness of the low-doped GaSb separate-confinement layers (SCLs). We
demonstrate room-temperature EDQEs approaching 45% for broad-area 7-stage ICLs with 800-nm-thick SCLs.
Atomic vapor cells with buffer gas have a number of advantages when employed as quantum memory blocks based on
the DLCZ (Duan-Lukin-Cirac-Zoller) protocol: operation slightly above room temperature, ease of handling, as well as
commercial availability. Nevertheless, the signal-to-noise ratio in the current implementations is severely limited by the
simultaneous presence of collisional fluorescence and the four-wave mixing noise. In our previous work, we have shown how to minimize the influence of the former on the writing process and provided an unambiguous demonstration of quantum memory lasting for 4 μs. An elegant approach to suppress the four-wave-mixing noise by pre-pumping to the state with the hyperfine sublevel with the maximum value was proposed by Walther et al., Int. J. Quantum Inform. 5, 51 (2007). Here we show that this approach is fundamentally limited by the cancellation of the Raman matrix elements involving the Fˊ= 1 and Fˊ= 2 levels, which occurs for all experimental conditions in the S → P transitions of all alkali atoms. A detuning that maximizes the signal-to-noise ratio is shown to exist for a given detector dark-count rate.
In this work, we use an analytical drift-diffusion model, coupled with detailed carrier transport and minority carrier lifetime estimates, to make realistic predictions of the conversion efficiency of InP-based triple junction cells. We evaluate the possible strategies for overcoming the problematic top cell for the triple junction, and make comparisons of the more realistic charge transport model with incumbent technologies grown on Ge or GaAs substrates.
We discuss two distinct approaches to realizing distributed-feedback (DFB) interband cascade lasers (ICLs) for
emission in the mid-IR. In the top-grating approach, the first-order gratings are produced by patterning high-index
germanium layers on top of narrow ridges with relatively thin top claddings. One 7-μm-wide device emitting at λ =
3.8 μm generated over 27 mW of cw single-mode output at 40°C, with a side-mode-suppression ratio <30 dB, while
at 80°C it still emitted <1 mW. At 20°C, a second device lased in a single spectral mode with <100 mW of drive
power. The tuning range was 21.5 nm with temperature and 10 nm with current. The corrugated-sidewall approach
relies on a fourth-order grating defined by optical lithography and etched into the sidewalls of the laser ridge. For a
13-μm-wide ICL ridge emitting at λ = 3.6 μm, the maximum power at T = 25°C was 55 mW, and at 40°C the device still produced 11 mW. We compare the physical requirements and performance characteristics for the two DFB
classes and conclude that top-grating DFBs generally exhibit greater stability and reproducibility, although the
efficiency is reduced by extra loss induced by modal overlap with the top metallization.
Semiconductor quantum wells and superlattices have found numerous applications in optoelectronic devices, such as lasers, LEDs and SOAs, and are an increasingly common feature of high efficiency solar cells and photodetectors. In this paper we will highlight some of the recent developments in the use of low-dimensional III-V semiconductors to improve the performance of photovoltaics by tailoring the bandgap of the junction. We also discuss novel structures designed to maximize photo-generated carrier escape and the application of quantum confinement to other components of the solar cell, such as tunnel junctions. Recent developments in type-II superlattices for photodetectors will also be discussed, including the graded-gap LWIR device based on the W-structured superlattices demonstrated at the Naval Research Laboratory.
Modeled results will be presented using the NRL BANDSTM integrated 8-band kp and Poisson solver, which was
developed for computing the bandstructures of superlattice and multi-quantum well photodiodes
The performance of mid-IR interband cascade lasers (ICLs) has been improved by introducing heavier doping into
the electron injector regions with the purpose of increasing the electron density in the active region to the level
commensurate with the active hole density. For devices emitting at wavelengths in the 3.6-3.9 μm range, the
improvements include pulsed room temperature (RT) threshold current density as low as 170 A/cm2, maximum cw
operating temperature as high as 109 °C, and RT cw input power as low as 29 mW. Epi-down-mounted ridges
display RT cw wall-plug efficiencies as high as 14.6% as well as emission of > 200 mW into a nearly diffraction-limited
beam. RT cw operation has also been demonstrated for considerably longer wavelengths extending to 5.7
μm with threshold power densities of ≈1kW/cm2, which are an order of magnitude lower than those in state-of-theart
quantum cascade lasers. The very low operating powers are expected to lengthen battery lifetimes and greatly
relax packaging and size/weight requirements for fielded chemical-sensing systems.
Quantum memory is regarded as one of the essential components in the fields of quantum computing and quantum
communication. Warm atomic vapor cells for quantum memory, as originally described in DLCZ (for Duan, Lukin,
Cirac, and Zoller) protocol, are appealing due to the perceived reduction in experimental complexity and commercial
availability. However, published studies on quantum memory using warm vapor cells were performed under widely
dissimilar experimental conditions and reported ambiguous results. In order for the memory to exhibit non-classical
behavior to a high degree of certainty, the cross-correlation value between the Stokes and anti-Stokes photons needs to
be greater than two. In this work we demonstrate quantum memory with cross-correlation value between the Stokes and
anti-Stokes photons greater than two lasting for 4 μs using warm Rb vapor with buffer gas for nearly co-propagating
write and read beams.
This work uses simulations to predict the performance of InAlAsSb solar cells for use as the top cell of triple
junction cells lattice matched to InP. The InP-based material system has the potential to achieve extremely high
efficiencies due the availability of lattice matched materials close to the ideal bandgaps for solar energy conversion.
The band-parameters, optical properties and minority carrier transport properties are modeled based on literature
data for the InAlAsSb quaternary, and an analytical drift-diffusion model is used to realistically predict the solar cell
performance.
Quantum memory is considered to be one of the key elements in the fields of quantum computing and quantum
communication. Warm atomic vapor cells for quantum memory in DLCZ (for Duan, Lukin, Cirac, and Zoller) protocol
are appealing due to the perceived reduction in experimental complexity and commercial availability. However, reported
results on quantum memory using warm vapor cells were done under widely different experimental conditions and
produced ambiguous results. In order for the memory to exhibit non-classical behavior, to a high degree of certainty, the
cross-correlation value between the Stokes and anti-Stokes photons needs to be greater than two. In this work we
demonstrate quantum memory with cross-correlation value between the Stokes and anti-Stokes photons greater than two
lasting for 4 μs using warm Rb vapor with buffer gas for nearly co-propagating write and read beams.
Neuronal optical excitation can provide non-contacting tools to explore brain circuitry and a durable stimulation
interface for cardiac pacing and visual as well as auditory sensory neuronal stimulation. To obtain accurate absorption
spectra, we scan the transmission of neurons in cell culture medium, and normalize it by subtracting out the absorption
spectrum of the medium alone. The resulting spectra show that the main neuronal absorption peaks are in the 3000-
6000nm band, although there is a smaller peak near 1450nm. By coupling the output of a 3μm interband cascade laser
(ICL) into a mid-IR fluorozirconate fiber, we can effectively deliver more than 1J/cm2 photon intensity to the excitation
site for neuronal stimulation.
Our simulations find that the active quantum wells in previous mid-IR interband cascade laser (ICL) designs have
invariably contained far more holes than electrons. Further modeling shows that the carrier populations can be
rebalanced by heavily doping the electron injector regions to levels more than an order of magnitude higher than in
any earlier devices. The experimental implementation of this strategy has dramatically improved nearly all ICL
performance characteristics. For devices emitting at wavelengths in the 3.6-3.9 μm range, this includes pulsed room
temperature (RT) threshold current density as low as 170 A/cm2, maximum cw operating temperature as high as 109
°C, RT cw output power as high as 159 mW, RT cw wallplug efficiency as high as 13.5%, and RT cw input power
as low as 29 mW. We also demonstrate RT cw operation to wavelengths as long as 5.7 μm. The extremely low input
power to reach threshold, which is more than 25 times lower than the best ever reported for a quantum cascade laser,
will strongly impact battery lifetimes and other system requirements in fielded chemical sensing applications.
An interband cascade laser design has been grown by molecular beam epitaxy using uncracked arsenic and antimony
sources. Lasers were fabricated into both broad-area and narrow-ridge devices, with cavity lengths ranging between 1
mm and 4 mm. At 300K, under low-duty-cycle pulsed conditions, threshold current densities for lasers with 2-mm cavity
lengths are as low as 395 A/cm2, with optical emission centered at a wavelength of ~3.82 μm at 300 K. Continuous-wave
(cw) performance of the narrow-ridge devices has been achieved for temperatures up to almost 60°C. We present results
of both pulsed (broad-area and ridge) and cw (ridge only) measurements on these lasers, including L-I-V, spectral,
cavity-length, and Hakki-Paoli analyses.
The interband cascade laser (ICL) is a unique device concept that combines the effective parallel connection of its
multiple-quantum-well active regions, interband active transitions, and internal generation of electrons and holes at a
semimetallic interface within each stage of the device. The internal generation of carriers becomes effective under
bias, and the role of electrical injection is to replenish the carriers consumed by recombination processes. Major
strides have been made toward fundamentally understanding the rich and intricate ICL physics, which has in turn led
to dramatic improvements in the device performance. In this article, we review the physical principles of the ICL
operation and designs of the active region, electron and hole injectors, and optical waveguide. The results for state-of-
the-art ICLs spanning the 3-6 μm wavelength range are also briefly reviewed. The cw threshold input powers at
room temperature are more than an order of magnitude lower than those for quantum cascade lasers throughout the
mid-IR spectral range. This will lengthen battery lifetimes and greatly relax packaging and size/weight requirements
for fielded sensing systems.
We discuss the current performance of long-wavelength infrared photodetectors based on type-II superlattices, and the projected characteristics for diffusion-limited operation. For optimized architectures such as graded-gap and abrupt-heterojunction designs, the dark currents are strongly dominated by Shockley-Read (SR) rather than Auger processes. A factor of 10 improvement over the demonstrated SR lifetimes would lead to a factor of 4 lower dark current than state-of-the-art HgCdTe devices.
KEYWORDS: Solar cells, Gallium arsenide, Multijunction solar cells, Solar energy, Indium gallium phosphide, Energy efficiency, Quantum wells, Coastal modeling, Performance modeling, Sun
The modeling of high efficiency, multijunction (MJ) solar cells away from the radiative limit is presented. In the model,
we quantify the effect of non-radiative recombination by using radiative efficiency as a figure of merit to extract realistic
values of performance under different spectral conditions. This approach represents a deviation from the traditional
detailed balance approximation, where losses in the device are assumed to occur purely through radiative recombination.
For lattice matched multijunction solar cells, the model predicts efficiency values of 37.1% for AM0 conditions and
52.8% under AM1.5D at 1 sun and 500X, respectively. In addition to the theoretical study, we present an experimental
approach to achieving these high efficiencies by implementing a lattice matched triple junction (TJ) solar cell grown on
InP substrates. The projected efficiencies of this approach are compared to results for the state of the art inverted-metamorphic
(IMM) technology. We account for the effect of metamorphic junctions, essential in IMM technology, by
employing reduced radiative efficiencies as derived from recent data. We show that high efficiencies, comparable to
current GaAs-based MJ technology, can be accomplished without any relaxed layers for growth on InP, and derive the
optimum energy gaps, material alloys, and quantum-well structures necessary to realize them.
The equations for the threshold-current density Jth, differential quantum efficiency ηd and maximum wallplug efficiency
ηwp,max for quantum-cascade lasers (QCLs) have been modified for electron leakage and backfilling. We used a thermalexcitation
model of "hot" injected electrons from the upper laser state to upper active-region energy states to calculate
leakage currents. Then the calculated characteristic temperature T0 for Jth was found to agree well with experiment for
both conventional and deep-well QCLs. The characteristic temperature T1 for ηd was deduced to be due to both electron
leakage and an increase in the waveguide-loss coefficient. For conventional mid-infrared QCLs ηwp,max is found to be
strongly temperature dependent which explains experimental data. By using a new concept: tapered active-region (TA),
deep-well QCLs have been optimized for virtual suppression of the electron-leakage currents. In turn, at room
temperature, for continuous-wave (CW)-operating, 4.5-5.0 μm-emitting TA QCLs we estimate the threshold current to
decrease by ~ 25 %, the active-region temperature rise at the ηwp,max point to decrease by ~ 30 %, and the single-ended,
ηwp,max value to become at least 22 %. Preliminary results from TA QCLs include T1 values as high as 454 K, over the
20-60 oC heatsink-temperature range.
The optical pumping injection cavity (OPIC) laser concept was developed to enhance the efficiency of optical pump
beam absorption, and this work focuses on epitaxial configurations designed for broadband absorption around 1850 nm,
an optimal pump wavelength for transmission through GaSb substrates that allows for epi-down mounting for improved
heat management, while minimizing the photon decrement. The OPIC devices presented in this work have
InAs/GaSb/InAs/AlSb type-II W active regions with a thicker GaSb/AlAsSb distributed Bragg reflector on top in order
to enhance reflection back into the active region for epi-down mounting. Results are presented for optical pumping at
1850 nm as well as for resonant optical pumping, as the cavity resonance varies with temperature due to shifts in lattice
constant, refractive index, and gain. Pumping at 1850 nm resulted in lasing from 78 K up through 310 K. At 78 K, the
actual pump cavity resonance is ~1840 nm, and with increasing temperature the resonance shifts to longer wavelengths
beyond 1850 nm. Emission wavelengths range from 3.59 μm at 78 K to 4.01 μm at 310 K for 1850 nm optical pumping.
The broadened OPIC configuration presents a distinct advantage over earlier reported OPIC devices as the broader
resonance allows for efficient emission across a wide temperature range for a single pump wavelength (e.g., 1850 nm),
providing over 400 nm of wavelength tuning. Results will be compared with a second broadened OPIC with emission
wavelengths beyond 4 μm that temperature tunes across the carbon dioxide spectral line at 4.2 μm.
In order to be commercially viable, the type-II superlattice (T2SL) LWIR focal plane array technology will require the
development of effective passivation of exposed surfaces. Here we investigate the relationship between the thickness
and composition of the native oxide at the T2SL-SiO2 interface and the diode performance in terms of sidewall
resistivity. Device performance is compared between samples with untreated surfaces, those for which the native oxides
have been removed at various intervals prior to SiO2 deposition, and samples for which oxide growth was promoted by
ozone exposure with and without a prior oxide strip. InAs- and GaSb-capped pieces were processed in an identical
manner and studied using X-ray photoelectron spectroscopy (XPS). From these spectra, the compositions and
thicknesses of the surface oxides just prior to SiO2 deposition were determined, complementing the electrical
characterization of devices. Correlation of the performance and surface composition is presented.
We report an experimental study of how the light-current characteristics and lateral mode properties of interband cascade lasers depend on ridge width. Narrower ridges provide greater heat dissipation due to lateral flow, along with operation in a single lateral mode. However,sidewall imperfections increase the cw threshold current density somewhat, from Jth = 582 A/cm2 at 300 K for an 11-µm-wide ridge to 713 A/cm2 and 1.07 kA/cm2 for 5- and 3-µm-wide ridges, respectively. The narrowest ridges similarly display a degradation of the slope efficiency. A 13-µm- wide ridge produced 45 mW per facet of cw output power and maximum wall-plug efficiency of 3.5% per facet at T = 20°C. A 5-µm-wide ridge with 3-mm cavity length and no facet coatings operated cw at = 3.5-µm to a new record temperature of 345 K for the 3 to 4-µm spectral range.
The equations for threshold-current density Jth and external differential quantum efficiency d of quantum cascade lasers (QCLs) are modified to include electron leakage and the electron-backfilling term corrected to take into account hot electrons in the injector. We show that by introducing both deep quantum wells and tall barriers in the active regions of 4.8-µm-emitting QCLs, and by tapering the conduction-band edge of both injector and extractor regions, one can significantly reduce electron leakage. The characteristic temperatures for Jth and d, denoted by T0 and T1, respectively, are found to reach values as high as 278 and 285 K over the 20 to 90°C temperature range, which means that Jth and d display 2.3 slower variation than conventional 4.5- to 5.0-µm-emitting, high-performance QCLs over the same temperature range. A model for the thermal excitation of hot injected electrons from the upper laser level to the upper active-region energy states, wherefrom some relax to the lower active-region states and some are scattered to the upper miniband, is used to estimate the leakage current. Estimated T0 values are in good agreement with experiment for both conventional QCLs and deep-well QCLs. The T1 values are justified by increases in both electron leakage and waveguide loss with temperature
Type-II strained layer superlattices (SLS) are a rapidly maturing technology for infrared imaging applications,
with performance approaching that of HgCdTe1,2,3,4. Teledyne Imaging Sensors (TIS), in partnership with the
Naval Research Laboratory (NRL), has recently demonstrated state-of-the-art, LWIR, SLS 256 × 256 focal
plane arrays (FPAs) with cutoff wavelengths ranging from 9.4 to 11.5 μm. The dark current performance of
these arrays is within a factor of 10-20 of (state-of-the-art) HgCdTe. Dark current characteristics of
unpassivated and passivated devices exhibit bulk-limited behavior, essential for FPA applications. TIS has
also demonstrated rapid substrate thinning processes for increased infrared transmission through the GaSb
substrate. In addition to this work, this presentation will discuss the recent developments of 1K x 1K LWIR
SLS FPAs.
Much has been accomplished in the last few years in advancing the performance of type-II superlattice (T2SL) based
infrared photodiodes, largely by focusing on device and heterostructure design. Quantum efficiency (QE) has increased
to 50% and higher by using thicker absorbing layers and making use of internal reflections, and dark currents have been
reduced by over a factor of ten by using bandstructure engineering to suppress tunneling and generation-recombination
(G-R) currents associated with the junction. With performance levels of LWIR T2SL photodiodes now within an order of
magnitude of that of HgCdTe (MCT) based technology, however, there is renewed interest in understanding fundamental
materials issues. This is needed both to move performance toward the theoretical Auger limit, and to facilitate the task of
transitioning T2SL growth from laboratories to commercial institutions. Here we discuss recent continuing efforts at
NRL to develop new device structures for enhanced detector performance, and to further our understanding of this
material system using advanced structural and electronic probes. Results from electron beam induced current (EBIC)
imaging and analysis of point defects in T2SL photodiodes will be presented, showing differentiated behavior of bulk
defect structures. We will also describe a study comparing intended vs. as-grown T2SL photodiode structures by crosssectional
scanning microscopy (XSTM). Using parameters extracted from the XSTM images, we obtain detailed
knowledge of the composition and layer structures through simulation of the x-ray diffraction spectra.
We review the state-of-the-art performance of interband cascade lasers emitting in the 3-5 μm spectral band and
discuss the prospects for future improvements. New five-stage designs produce a combination of pulsed roomtemperature
threshold current densities of 400-500 A/cm2 and internal losses as low as ≈ 6 cm-1 for broad-area
devices. A 4.4-μm-wide ridge fabricated from one of these wafers and emitting at 3.7 μm lased cw to 335 K, which
is the highest cw operating temperature for any semiconductor laser in the 3.0-4.6 μm spectral range. A 10-μm-wide
ridge with high-reflection and anti-reflection facet coatings produced up to 59 mW of cw power at 298 K, and
displayed a maximum wall-plug efficiency of 3.4%. Corrugated-sidewall distributed-feedback lasers from similar
material produce 45 mW of cw power in a single spectral mode at -20°C, with maximum wall-plug efficiency of
7.6%. The current tuning range for temperatures between 0 and 25°C is ≥11 nm.
In this work we show that by using both deep quantum wells and tall barriers in the active regions of quantum cascade
(QC)-laser structures and by tapering the conduction-band edge of both injector an extractor regions one can
significantly reduce the leakage of the injected carriers. Threshold-current, Jth and differential-quantum efficiency, ηd
characteristic temperatures, T0 and T1, values as high as 278 K and 285 K are obtained to 90 °C heatsink temperature,
which means that Jth and ηd vary ~ 2.5 slower over the 20-90 °C temperature range than in conventional QC devices.
Modified equations for Jth and ηd are derived. In particular, the equation for ηd includes, for the first time, its dependence
on heatsink temperature. A model for the thermal excitation of injected carriers from the upper lasing level to upper
active-region energy states from where they relax to lower active-region energy states or get scattered to the upper Γ
miniband is employed to estimate carrier leakage. Good agreement with experiment is obtained for both conventional
QC lasers and deep-well (DW)-QC lasers.
Lifetimes, Auger coefficients, and internal losses were deduced for 25 different type-II "W" interband cascade laser
structures, from correlations of the experimental threshold current densities and slope efficiencies with calculated
threshold carrier densities and optical gains. The room-temperature Auger coefficients for a number of lowthreshold
devices emitting at wavelengths from 2.9 μm to 5.2 μm fall in the narrow range 3-11 × 10-28 cm6/s, which
represents a much stronger suppression of Auger decay than was implied by most earlier experiments and theoretical
projections. The estimated internal loss is lowest at intermediate wavelengths, and the most recent designs display
additional reduction to as little as 8 cm-1 at 300 K.
Advances in the development of mid-IR antimonide type-II "W" interband cascade lasers (ICLs) have recently led
to the first demonstration of continuous wave operation at room temperature. The 5-stage narrow-ridge Auelectroplated
ICL emitted at λ= 3.75 μm produced over 10 mW of cw power at 300 K and operated to 319 K. The
considerable increase in Tmax was realized by carefully optimizing both the design and the MBE growth of these
complicated multilayer structures. The internal loss was decreased by reducing the doping in the claddings and
separate-confinement regions, and then using fewer stages to take advantage of the lower dissipated power density
while still having enough gain to reach threshold. We find that the improved properties are similarly available in
devices spanning the spectral window of at least 3.2-4.2 μm.
In this work we present the characteristics of a novel type of quantum-cascade (QC) laser: the deep-well (DW) QC
device, which, unlike conventional QC lasers, contains a superlattice of quantum wells and barriers of different
composition, respectively. The fabrication of DW-QC devices is made possible by the use of metal-organic chemical
vapor deposition (MOCVD), a crystal growth technique which allows one to easily vary the composition of wells and
barriers within QC structures, thus providing significantly increased flexibility in optimizing the device design. We have
designed such varying-composition QC structures to have deep quantum wells in and tall barriers in and around the
active region. DW- QC laser structures have fabricated into 19 μm-wide ridges and 3 mm-long chips. Threshold-current
densities as low as 1.5 kA/cm2 are obtained at room temperature in the 4.6-4.8 μm wavelength region. In conventional
QC lasers emitting in the 4.5-5.5μm range there is substantial thermionic carrier leakage from the upper laser level to the
continuum, as evidenced by a significant decrease in the slope efficiency above 250 K, which is understandable given
the relatively small (i.e., ~ 200 meV) energy differential, δE, between the upper lasing level and the top of the exit
barrier. For the DW design carrier leakage is suppressed due to deep active wells and tall barriers, such that δE reaches
values in excess of 400 meV. Preliminary results include a threshold-current characteristic temperature, T0, value of 218
K over the temperature range: 250- 340 K.
Intersubband Quantum-Box (IQB) lasers; that is, devices consisting of 2-D arrays of ministacks (i.e., 2-4 stages) intersubband QB emitters are proposed, as an alternative to 30-stage quantum-cascade (QC) devices, as sources for efficient room-temperature (RT) emission in the mid-infrared (4-6 µm) wavelength range. Preliminary results include: 1) the design of devices for operation with 50% wallplug efficiency at RT; 2) realization of a novel type of QC device: the deep-well (DW) QC laser, that has demonstrated at =4.7µm low temperature sensitivity of the threshold current, a clear indication of suppressed carrier leakage; 3) the formation of 2-D arrays at nanopoles by employing nanopatterning and dry etching; 4) the formation of 40nm-diameter, one-stage IQB structures on 100nm centers by preferential regrowth via metal-organic vapor phase epitaxy (MOVPE).
The use of 1.55μm lasers for free space optical links has become well established. While one expects there to be
advantages to operating at 3.6μm, namely higher transmission through water vapor and reduced scintillation, the
availability of both lasers and detectors at the mid IR wavelength is not as mature as those available at the telecomm
choice of 1.55μm. However, there are potential schemes for using frequency conversion to probe the atmosphere in the
mid-ir but to detect back in the near-ir.
A sequence of experiments has been conducted, over a 16km one-way link across the Chesapeake Bay, to directly
compare the intensity variances and the power spectrum imposed by the atmosphere at the two wavelengths. An
interband cascade laser was used which operated at a wavelength of 3.6μm and had an output power of 100mW. The
1.55μm system used standard telecomm parts. Data were recorded simultaneously from both systems at 4kHz and were
digitized using a 16-bit card. A telescope measured the angle-of-arrival variance of the 1.55mm beam in order to give a
measure of the atmospheric structure constant Cn2. In addition a visibility monitor and weather station were usually
operational at each end of the link.
Electrically-pumped photonic-crystal distributed-feedback lasers with interband-cascade active regions operating in
single spectral mode at 3.3 μm are demonstrated. At 78 K, a stripe of width 400 μm emits up to 67 mW of cw power
into a single spectral mode with side-mode suppression ratio ≈ 27 dB. The full-width at half-maximum of the farfield
divergence angle is ≈ 0.5°, which combined with the near-field profile yields an effective M2 of 1.7-2.0.
Recent advances in the development of mid-IR antimonide type-II "W" interband cascade lasers have led to a
considerably improved high-temperature operation of the devices. We report an experimental investigation of four
interband cascade lasers with wavelengths spanning the mid-infrared spectral range, i.e., 2.9-5.2 μm near room
temperature in pulsed mode. One broad-area device had a pulsed threshold current density of only 3.8 A/cm at 78 K
(λ = 3.6 μm) and 590 A/cm2 at 300 K (λ = 4.1 μm). The room-temperature threshold for the shortest-wavelength
device (λ = 2.6-2.9 μm) was even lower, 450 A/cm2. A cavity-length study of the lasers emitting at 3.6-4.1 μm
yielded an internal loss varying from 7.8 cm-1 at 78 K to 24 cm-1 at 300 K, accompanied by a decrease of the internal
efficiency from 77% to 45%. Preliminary cw testing led to a narrow-ridge device from one of the wafers with
emission at λ = 4.1 μm operating to 288 K, a new record for interband devices in this wavelength range.
Measurement of the isotopic composition of atmospheric methane is a valuable tool for understanding the sources and sinks of the global carbon budget. One promising carbon isotope ratio measurement technology is optical spectroscopy using inter-band cascade (IC) lasers. Ongoing development of these light sources has the goal of providing, from a package operating near room temperature, a single mode laser source in the wavelength range of 3 &mgr;m. The spectral features of methane are sufficiently strong at this wavelength that a path length of about 100 m should suffice for measuring 12- and 13-C isotopes in air without pre-concentrating the sample. Experimental IC lasers are described and their use for isotope sensing by wavelength modulation spectroscopy is evaluated.
A critical step in developing type-II superlattice (T2SL) based LWIR focal plane array (FPA) technology is to achieve high performance levels in FPA pixel-sized devices having 20-40 μm pitch. At this scale, device performance tends to be limited by surface effects along mesa sidewalls which are etched to provide pixel isolation. While control of surface leakage has been achieved for MWIR T2SLs, as evidenced by the availability of commercially produced FPAs, the same cannot be said for LWIR T2SLs. Several groups have approached this problem as strictly a matter of surface treatment, including cleaning, chemical treatment, and dielectric coating or epitaxial overgrowth, but with limited success. Here we describe an approach based on shallow-etch mesa isolation (SEMI), which takes advantage of bandgap grading to isolate devices without exposing narrow-gap LWIR regions on diode mesas sidewalls. The SEMI process consists of defining mesa diodes with a shallow etch that passes only 20-100 nm past the junction of a graded-gap "W"-structured type-II superlattice p-i-n structure, where the bandgap remains large (>200 meV). A second, deeper etch is then used to define a trench along the chip border for access to the p-contact. As a result, SEMI diodes have only MWIR layers exposed along sidewalls, while the LWIR regions remain buried and unexposed. We also discuss an investigation of surface passivation of GaSb with sulfur using thioacetamide.
We study AlxGa1-xN/AlN/GaN heterostructures with a two-dimensional-electron-gas (2DEG) grown on different GaN
templates using low-temperature magneto-transport measurements. Heterostructures with different Al compositions are
grown by metal-organic vapor phase epitaxy (MOVPE) on three different templates; conventional undoped GaN (u-
GaN), epitaxial lateral overgrown GaN (ELO-GaN), and in situ ELO-GaN using a SixNy nanomask layer (SiN-GaN).
Field-dependent magneto-resistance and Hall measurements indicated that in addition to 2DEG, the overgrown
heterostructures had a parallel conducting layer. The contact resistance for the parallel channels was large so that it
introduced errors in the quantitative mobility spectrum analysis (QMSA) of the data. Notwithstanding complexities
introduced by parallel conducting channels in mobility analysis in SiN-GaN and ELO-GaN samples, we were able to
observe Shubnikov-de Haas (SdH) oscillations in all samples, which confirmed the existence of 2DEGs. To characterize
the parallel channel, we repeated the transport measurements after the removal of the 2DEG by etching the
heterostructure. The 2DEG carrier density values were extracted from the SdH data, whereas the zero-field 2DEG
conductivity was determined by subtracting the parallel channel conductivity from the total conductivity. The resulting
2DEG mobility was significantly higher (about a factor of 2) in the ELO-GaN and SiN-GaN samples as compared to the
standard control sample. The mobility enhancement is attributed to the threading dislocation reduction by both ELO
techniques.
Significant recent advances in the high-temperature, high-power performance of type-II antimonide interband
cascade lasers (ICLs) operating in the mid-infrared are reported. A 5-stage ICL with a 12-&mgr;m ridge width and Au
electroplating for improved epitaxial-side-up heat sinking operates cw to a maximum temperature of 257 K, where
the emission wavelength is 3.7 &mgr;m. A similar device with a ridge width of 22 &mgr;m emits > 260 mW per facet for cw
operation at 80 K (λ = 3.4 &mgr;m) and 100 mW at 200 K (λ = 3.6 &mgr;m). Beam qualities for the narrowest ridges
approach the diffraction limit. A single-mode output power of 41 mW has been obtained at T = 120 K and λ ≈ 3.44
μm from a 13-&mgr;m-wide ICL patterned with a Ge distributed-feedback grating. The side mode suppression ratio at
the maximum power is 23 dB, and the linewidth of 0.1 nm is instrument-limited. An alternate contacting geometry
yielded robust single-mode output over a broad range of currents and temperatures, and current tuning of the
wavelength by up to 17 nm.
Recently we have achieved significant improvements in the performance of LWIR type-II superlattice photodiodes,
with discrete devices beginning to demonstrate dynamic impedance-area product (R0A) levels approaching the
MCT trend line and quantum efficiency exceeding 30% in devices without anti-reflection coatings. We discuss the
key innovations that have led to these improvements, including modified W-structures, band-gap grading, and
hybrid superlattices.
Significant recent advances in the high-temperature, high-power performance of type-II antimonide interband cascade lasers (ICLs) operating in the mid-infrared are reported. A 5-stage ICL with a 12μm ridge width and Au electroplating for improved epitaxial-side-up heat sinking operates cw to a maximum temperature of 257 K, where the emission wavelength is 3.7 μm. A similar device with a ridge width of 22 μm emits > 260 mW per facet for cw operation at 80 K (λ = 3.4 μm) and 100 mW at 200 K (λ = 3.6 μm). Beam qualities for the narrowest ridges approach the diffraction limit. The recent development of type-II "W" photodiodes for the long-wave infrared is also reviewed. A "W" photodiode with an 11.3 μm cutoff displayed a 34% external quantum efficiency (at 8.6 μm) operating at 80 K. A graded-gap design of the depletion region is shown to strongly suppress dark currents due to tunneling and generation-recombination processes. The median dynamic impedance-area product of 216 Ω-cm2 for 33 devices with 10.5 μm cutoff at 78 K is comparable to that for state-of-the-art HgCdTe-based photodiodes. The sidewall resistivity of ≈70 kΩ-cm for untreated mesas is also considerably higher than previous reports for passivated or unpassivated type-II LWIR photodiodes, apparently indicating self-passivation by the graded bandgap.
Whereas high-power operation (> 1 W of cw output power at 200 K) has been demonstrated for quantum cascade lasers emitting at λ = 4.7-6.2 μm, those devices generally exhibited multiple longitudinal modes. Recently, a distributed-feedback quantum cascade laser operating in a single spectral mode at λ = 4.8 μm and at temperatures up to 333 K has been reported. In the present work, we provide detailed measurements and modeling of its performance characteristics. The sidemode suppression ratio exceeds 25 dB, and the emission remains robustly single-mode at all currents and temperatures tested. Cw output powers of 99 mW at 298 K and 357 mW at 200 K are obtained at currents well below the thermal rollover point. The slope efficiency and subthreshold amplified spontaneous emission spectra are shown to be consistent with a coupling coefficient of no more than κL ≈ 4-5, which is substantially lower than the estimate of 9 based on the nominal grating fabrication parameters.
Recent improvements in material quality and design have led to large improvements in the quantum efficiency (QE) of long-wave infrared (LWIR) photodiodes based on W-structured type-II superlattices (WSL), which now have achieved external QE of up to 35% on an 11.3 μm cutoff photodiode operating at 80K. While single band and dual band WSLs have been demonstrated with cutoff wavelengths out to 17 μm, the initial devices also showed significant losses of photo-excited carriers resulting in QE levels of ≤ 10%. Here we describe recent results in which these losses have been dramatically reduced by modifying the WSL barrier layers to increase the mini-band width and improve the material properties. An additional 35-55% increase in QE also resulted from the use of semitransparent Te doped n-GaSb substrates that allowed for IR reflections off the backside from the Au plated chip carrier. A series of PIN photodiodes using the improved WSL, with intrinsic regions from 1 to 4 μm thick, were used to study minority carrier transport characteristics in the new structure. As a result of the improved design and material properties, the electron diffusion length in the undoped i-region, as determined from a theoretical fit to the thickness-dependent data, was 3.5 μm, allowing for much higher collection efficiency in PIN photodiodes with intrinsic regions up to 4 μm thick.
The I-V characteristics, lasing thresholds, and wallplug efficiencies of type-II "W" mid-IR diode lasers from 16 different wafers were studied in order to determine the influence of various device parameters. At T = 90 K, the wallplug efficiency for a 1-mm-long gain-guided device was > 10% and the slope efficiency was 142 mW/A (38% external quantum efficiency). When a 22-μm-wide ridge was lithographically defined on a 5-period "W" laser with a p-GaSb etch stop layer, the maximum cw operating temperature increased to 230 K. We also investigated 5-stage and 10-stage interband cascade lasers containing "W" active quantum wells. For 10-stage devices, the low-temperature threshold current densities were somewhat higher than in the "W" diodes while at higher temperatures they were slightly lower. The threshold voltage was only ≈ 0.1 V larger than the photon energy multiplied by the number of stages, corresponding to a voltage efficiency of > 96%, while the differential series resistance-area product above threshold was as low as 0.21 mΩ.cm2 at 100 K. At T = 78 K, the cw slope efficiency was 0.48 mW/A (126% external quantum efficiency), and a maximum cw power of 514 mW was produced by an epi-side-up-mounted 2-mm-long 10-stage laser cavity with uncoated facets. A 5-stage 2-mm-long interband cascade laser produced ≈ 700 mW of output power at 80 K, with a maximum wallplug efficiency of 20% per facet.
Multiband detection capability is a critical attribute of practical infrared (IR) sensing systems for use in missile defense detect-and-track applications. This capability, already demonstrated in mercury-cadmium telluride (MCT) photodiodes and quantum well infrared photodetectors (QWIPs), has not previously been explored in type II-superlattices (T2SLs), a newer system which is under consideration to meet next-generation sensor needs. Like QWIPs, T2SLs are composed of layers of III-V compound semiconductors grown by molecular beam epitaxy (MBE), and have an infrared gap that is determined primarily by the layer thicknesses. With the exceptional control of MBE over layer thicknesses and the ability to grow multiple bandgap structures under compatible growth conditions, T2SL-based multiband IR focal plane arrays (FPAs) are expected to have advantages in spectral control and pixel-to-pixel uniformity over MCT. Additionally, T2SLs have intrinsically higher quantum efficiency than QWIPs, in which the optical selection rules for intersubband transitions forbid the absorption of normally incident light.
Here we describe the first results for a T2SL dual band detector with independent long-wave and very-long-wave infrared responsivity bands, with cutoffs of 11.4 and 17 μm respectively. The p-n-p device contains "W"-structured T2SL (WSL) active regions for enhanced band selectivity, owing to the quasi-two-dimensional density of states for WSLs. Photodetector results are demonstrated using a maskset designed to fabricate single-band diodes, 3-terminal dual band devices, and 2-terminal band selectable devices to comply with different dual band FPA read-out architectures.
Dilute nitride type-II "W" structures have potential for lasing at 1.55 microns (on GaAs substrates) and in the mid-infrared (3-6 microns, on InP substrates). The former active regions utilize (In)GaAsN/GaAsSb/(In)GaAsN/GaAs quantum wells, whereas the latter are based on InAsN/GaAsSb/InAsN/GaInP structures. Following a review of the theoretical rationale, we will present some preliminary MOCVD growth results for the GaAs-based type-II structures, along with their characterization by x-ray, TEM, and photoluminescence. The experimental energy gaps corresponding to the layer compositions determined from characterization are in good agreement with calculations based on the 10-band k×p formalism.
W-structured type-II superlattices (W-SLs) were initially developed to increase the gain of mid-wave infrared (MWIR) lasers. The design addressed the reduced optical transition matrix elements due to the spatial displacement between valence and conduction band wavefunctions in the type-II superlattice (T2SL), and further improved the differential optical gain by providing a mostly two-dimensional density of states. As a result, W-SL and W interband cascade lasers have lower thresholds and higher pulsed and cw operating temperatures than any other III-V interband MWIR lasers. These same features give W-SLs desirable properties for IR detectors, and here we report for the first time on characteristics of W-SLs used for long-wave and very long-wave IR photodiodes. IR transmission measurements of W and conventional T2SL photodiodes revealed absorption characteristics that are well described by theory, including line shape and peak absorption coefficient values which are about a factor of 2 greater in the W-SLs. Similarly, the low temperature photoluminescence shows much higher and sharper emission intensity in the W-SLs. While the W-SLs have demonstrated superior optical properties, as predicted, additional work is needed to achieve higher detector quantum efficiency. Results suggest that the excess carrier collection in the W-structures is reduced with respect to similar T2SL structures, especially for the lowest energy state. Possible mechanisms of excess carrier loss, as well as new designs to improve charge collection, in the W-SL, will be discussed.
We report the cw operation of quantum cascade lasers that do not require cryogenic cooling and emit at λ = 4.7-6.2 μm. At 200 K, more than 1 W of output power is obtained from 12-μm-wide stripes, with a wall-plug efficiency (ηwall) near 10%. Room-temperature cw operation has also been demonstrated, with a maximum output power of 640 mW (ηwall = 4.5%) at 6 μm and 260 mW (ηwall = 2.3%) at 4.8 μm. Far-field characterization indicates that whereas the beam quality remains close to the diffraction limit in all of the tested lasers, in the devices emitting at 6.2 μm the beam tends to steer by as much as 5-10° degrees in either direction with varying temperature and pump current.
Mid-infrared “W” quantum-well diode lasers with reduced turn-on voltages are reported. Devices with coated facets operated in continuous-wave mode up to 195 K, where the emission wavelength was 3.56 microns. At 78 K the threshold current density was 67 A/cm2, the maximum output power was 198 mW, and the maximum slope efficiency was 106 mW/A. One of these lasers was used to detect methane, by exploiting the absorption band in the vicinity of 3.3 microns. Preliminary measurements demonstrated detection of methane at partial pressures down to 7 x 10-7 atm. in a nitrogen atmosphere.
Photonic-crystal distributed-feedback (PCDFB) lasers can potentially operate in a single optical mode that remains coherent over extremely large device areas, e.g., > 1 mm2, in spite of the effects of filamentation induced by the linewidth enhancement factor. Two-dimensional diffraction is induced by gratings that are defined on a rectangular lattice for edge emission, or on a hexagonal or square lattice for surface emission. Numerical simulations based on original algorithms reveal that whereas minimizing that product is almost always advantageous in edge-emitting lasers, an optimized surface-emitter should have an intermediate value. We also review recent experimental demonstrations of both 2nd-order and 1st-order optically pumped broad-stripe PCDFB lasers with “W” active regions that emit in the mid-IR.
Gain in broad area mid-infrared diode W lasers ((lambda) =3- 3.1micrometers ) has been measured using lateral mode spatial filtering combined with the Hakki-Paoli approach. The internal optical loss of approximately equals 19cm-1 determined from the gain spectra was the same for devices with either 10- or 5-period active regions and nearly constant in the temperature range between 80 and 160K. Analysis of the differential gain and spontaneous emission spectra shows that the main contribution to the temperature dependence of the threshold current is Auger recombination, which dominates within almost the entire temperature range studied (80-160K).
Photonic-crystal distributed-feedback (PCDFB) lasers, in which the DFB grating is defined on a two-dimensional lattice, have the potential to provide near-diffraction-limited, spectrally pure sources of radiation. The conventional 1D DFB laser and also the angled-grating DFB (a-DFB) laser are special cases of the PCDFB geometry. For a first proof-of-principle demonstration, optical lithography and dry etching were used to pattern a 2nd-order two-dimensional rectangular lattice whose grating was tilted by 20 degree(s) relative to the facet normal. The antimonide type-II W active region emitted at (lambda) = 4.6-4.7 micrometers . For pulsed optical pumping, the emission line was much narrower (7-10 nm) than those of Fabry-Perot and (alpha) -DFB lasers fabricated from the same wafer, and the beam quality was enhanced by as much as a factor of 5 compared with the (alpha) -DFB. The observation of two distinct lines in the PCDFB spectrum is attributed to a near-degeneracy of grating resonances at two different symmetry points of the Brillouin zone for the rectangular lattice. Quantum-cascade (QC) PCDFB lasers are shown to be particularly attractive in the mid-IR spectral range since their linewidth enhancement factor, which governs the carrier-induced refractive index change, is close to zero. Using a time-domain Fourier-transform algorithm, we estimate that rectangular-lattice QC lasers should emit in a single mode up to a stripe width of approximately equals may be employed to maintain spectral and spatial coherence over stripes as wide as 3 mm.
We have studied the far-field characteristics of mid- infrared angled-grating distributed feedback ((alpha) -DFB) lasers with W active regions as a function of etch depth, stripe width, and optical pumping intensity. Whereas near- diffraction-limited output is obtained for 50 micrometers stripes at 10 times threshold, the beam quality degrades rapidly when either the stripe width or the pump intensity is increased. A key finding is that most of the degradation may be attributed to the onset of Fabry-Perot-like lasing modes that propagate along the direct path normal to the facets. We further show that these parasitic modes may be effectively eliminated by using ion bombardment to create angled virtual mesas surrounded by loss regions. The bombarded structures show substantial improvement of the beam quality for wide pump stripes and high pump intensities, with only a modest reduction in the efficiency.
Recent progress towards the realization of high-power, non- cryogenic (quasi-)cw mid-IR lasers based on the `W' configuration of the active region is reported. Type-II diodes with AlGaAsSb broadened-waveguide separate confinement regions are the first III-V interband lasers to achieve room-temperature pulsed operation at a wavelength longer than 3 micrometers . For cw operation, Tmax was 195 K and Pout equals 140 mW was measured at 77 K. Optically- pumped W lasers recently attained the highest cw operating temperatures (290 K) of any semiconductor laser emitting in the 3 - 6 micrometers range. For a (lambda) equals 3.2 micrometers device at 77 K, the maximum cw output power was 0.54 W per uncoated facet. In order to maximize the absorption of the pump in the active region, an optical pumping injection cavity structure was used to create an etalon cavity for the 2.1 micrometers pump beam. The pulsed incident pump intensity at threshold was only 8 kW/cm2 at 300 K for this edge- emitting mid-IR laser. The differential power conversion efficiency was 9% at 77 K and 4% at 275 K, which indicates promising prospects for achieving high cw output powers at TE-cooler temperatures following further optimization.
Optically-pumped type-II W lasers have exhibited improved high-temperature performance throughout the wavelength range of 2.7 micrometer to 7.3 micrometer. Low duty cycle pumping at 2.1 micrometer yielded maximum operating temperatures as high as 360 K at (lambda) less than or equal to 4 micrometer for 3 devices, with peak output powers exceeding 1.5 W at ambient temperature. Internal losses of 90 cm-1 at 300 K were seen for one device and suppressed Auger recombination coefficients were observed for all three. Pulsed operation at wavelengths as long as 7.3 micrometer was seen in another device which had a maximum operating temperature of 220 K. For 1.064 micrometer optical pumping, the same laser was able to operate in continuous-wave (cw) mode to 130 K. Cw operation was also observed at temperatures as high as 290 K for lambda approximately equals 3.0 micrometer. Maximum cw output powers (per uncoated facet) of 260 mW at (lambda) equals 3.1 micrometer and 50 mW at (lambda) equals 5.4 micrometer were observed at T equals 77 K. With further improvements in the design and growth quality of these W laser structures, it is projected the cw output powers of 0.5 W or more should be achievable at thermoelectric cooler temperatures.
A 2.9 micrometer superlattice diode laser with an InAs/GaSb/Ga0.75In0.25Sb/GaSb active region displayed high temperature operation and low current injection thresholds. The maximum operating temperature was 260 K, and at 200 K the threshold current density was 1.1 kA/cm2 and the quantum efficiency greater than 15%. The peak output power per facet for this laser exceeded 800 mW at 100 K and 200 mW at 200 K for a 0.05% duty cycle. For two similar lasers, internal losses were extracted from optical pumping experiments. The first laser was designed to minimize Auger recombination by avoiding resonances between the bandgap and intervalence transitions (at zone center), while the second was designed to maximize these resonances. Internal losses for the Auger minimized (maximized) laser diode were 14(10) cm-1 at T equals 100 K, and rose rapidly to 51(120) cm-1 at 200 K. However, Auger coefficients were suppressed (less than or equal to 1.6 X 10-27 cm6/s at T equals 260 K) for both samples when compared to a type-I material with a similar bandgap. For optical pumping, peak output powers up to 6.5 W per facet at 100 K and 3.5 W per facet at 180 K were obtained for these samples at lambda approximately equals 3.1 micrometer.
Recently, we demonstrated a new type of quantum cascade lasers based on interband transitions in type-II heterostructures. It takes advantage of the broken-gap band alignment in the InAs/Ga(In)Sb heterostructure to recycle electrons from the valence band back to the conduction band, thus enabling sequential photon emission from active regions stacked in series. A peak optical output power of approximately 0.5 W/facet from a broad area gain-guided interband cascade laser with a threshold current density of 290 A/cm2, and a slope of 211 mW/A per facet, corresponding to a differential external quantum efficiency of 131%, were obtained at 80 K and at a wavelength of approximately 3.9 micrometer. Differential quantum efficiencies exceeding 200% were also observed from mesa structure lasers. Comparable device performance was also achieved based on a 'W' configuration cascade laser at approximately 2.9 micrometer, which has been operated at temperatures up to 225 K. Another W interband cascade laser has displayed lasing at 3.6 micrometer and nearly to room temperature (286 K).
Jerry Meyer, Christopher Felix, Jay Malin, Igor Vurgaftman, Craig Hoffman, C.H. Lin, Paul Chang, Stefan Murry, Rui Q. Yang, Shin Shem Pei, L. Ram-Mohan
A series of optically-pumped type-II quantum well lasers with emission wavelengths between 3.2 micrometers and 4.5 micrometers have displayed stimulated emission up to ambient operating temperatures. The 4-constituent design combines the advantages of excellent carrier confinement, potential for significant Auger suppression, and a 2D density-of-states for both electrons and holes. For a device emitting at 4.5 micrometers , the characteristic temperature was 41 K and a peak output power exceeding 2 W/facet was observed at 200 K. Auger coefficients extracted from the threshold pump intensity confirm that Auger losses at 300 K were suppressed by at least a factor of two. We also discuss modeling results for a type-II interband cascade laser structure which is predicted to yield much higher output powers and operating temperatures than conventional bipolar diode lasers, as well as lower threshold currents than the intersubband quantum cascade laser.
Over the last decade considerable advances have been made in the area of semiconductor lasers as a result of tailoring the electronic structure of the active medium. This has been accomplished through the use of quantum confinement and built-in strain. There has been less emphasis on altering the photonic properties to improve laser performance. In this paper we examine the potential of a surface-emitting microcavity structure with submicron lateral dimensions for improving laser performance. We find that as the lateral dimensions are decreased, the photon density of states starts to change. In particular, strongly resonant states associated with Bragg reflection begin to dominate the photon spectrum. By placing the resonance peak close to the gain peak in the active quantum well region, a number of laser properties can be altered. The dimensions at which the changes start to be significant is about (lambda) /na, where na is the refractive index of the active region. A study of how the threshold current, dynamic characteristics and laser linewidth change as a function of the microcavity dimensions is presented. Our studies show that the spontaneous emission factor (beta) approaches a value of approximately equals 0.5 for small structures with high mirror reflectivities. This in turn results in essentially zero threshold lasing for a microcavity with lateral dimensions < 0.3 micrometers (for emission at 1.3 eV). The laser linewidth increases as (beta) decreases, but the increase is not proportional to (beta) , and even for small structures, the linewidth is expected to be in the range of 100 MHz to 1 GHz, which may be adequate for many applications. The -3 dB response of the 0.3 micrometers laser exceeds 40 GHz.
In semiconductor lasers, hot carriers are injected into the active region of the device, and their thermalization is essential for the laser performance. In this work, carrier thermalization is studied for quantum well, wire and dot laser stuctures. Low threshold considerations dictate the transition from bulk to quantum well to quantum wire to quantum dot systems. However, we find that carrier thermalization times increase as the dimensionality of the structures is reduced. The equilibration times are approximately equals 1 ps in bulk, approximately equals 10 ps in quantum wells, approximately equals 30 ps in quantum wires and approximately equals 100 ps in quantum dots. The increase of the thermalization times is responsible for serious limitations of the high-speed response of the quantum-confined laser structures. The implications of the slow carrier thermalization are discussed.
Carrier transport and recombination dynamics are seen to be the intrinsic limitations to the performance of quantum well lasers. The carrier relaxation times as a function of quantum well width were measured in laser structures using a streak camera. Auger recombination rates were experimentally determined in compressively strained InxGa1-xAs/InGaAsP/InP quantum wells from the large signal modulation of single mode lasers. In order to overcome the intrinsic limitations in present semiconductor laser designs, a new device concept has been demonstrated: the tunneling injection quantum well laser, in which the carriers are injected into the active lasing subband by resonant and sequential tunneling. The highest 3 dB modulation bandwidth (12.5 GHz) and the highest differential gain (6 X 10-16 cm2) for a single quantum well laser have already been demonstrated. To realize threshold currents of much less than 1 mA, quantum wire lasers are required. We present theoretical and experimental results on the performance characteristics of quantum wire lasers. The experimental structures are being realized in the InxGa1-xAs/GaAs system by MBE growth and regrowth and electron beam lithography.
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