Prof. Seth R. Marder Profile

Prof. Seth R. Marder

Professor/Chemistry/Materials Science at Univ of Colorado Boulder

SPIE Involvement:

Conference Program Committee | Author

Publications (59)

Proceedings Article | 1 August 2021 Presentation

Polyethylenimine cathode interlayer: influence of solvent on functionality and single-step formation from polymer blend solution

Andreas Opitz, Dominique Lungwitz, Raphael Schlesinger, Sujitkumar Bontapalle, Susy Varughese, Keli Fabiana Seidel, Thomas Krüger, Jan Behrends, Seth Marder, Norbert Koch

Proceedings Volume 11809, 118090Q (2021) https://doi.org/10.1117/12.2593881

KEYWORDS: Polymers, Electrodes, Interfaces, Zinc oxide, Transparency, Resistance, Perovskite, Optoelectronics

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Proceedings Article | 1 August 2021 Presentation

Disentangling bulk and interface phenomena in a molecularly doped polymer semiconductor

Dominique Lungwitz, Thorsten Schultz, Claudia E. Tait, Jan Behrends, Swagat Mohapatra, Stephen Barlow, Seth R. Marder, Andreas Opitz, Norbert Koch

Proceedings Volume 11809, 1180909 (2021) https://doi.org/10.1117/12.2593646

KEYWORDS: Semiconductors, Polymers, Doping, Interfaces, N-type semiconductors, Electrodes, Tin, Resistance, Oxides, Organic semiconductors

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Proceedings Article | 5 March 2021 Presentation

Hyperfine versus spin-vibronic coupling: or do both drive TADF?

Bluebell Drummond, Richard Friend, Emrys Evans, Patrick Conaghan, William Myers, Seth Marder

Proceedings Volume 11683, 116830I (2021) https://doi.org/10.1117/12.2579572

KEYWORDS: Lens design, Thin films, Thin film devices, Spectroscopy, Solid state electronics, Physics, Organic light emitting diodes, Optical spectroscopy, Molecules, Molecular interactions

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Proceedings Article | 18 September 2018 Presentation

Redox-active molecules as electrical dopants for OLED transport materials (Conference Presentation)

Stephen Barlow, Michael Fusella, Samik Jhulki, Antoine Kahn, Norbert Koch, Elena Longhi, Kyung Min Lee, Xin Lin, Seth Marder, Karttikay Moudgil, Barry Rand, Chad Risko, Berthold Wegner, Fengyu Zhang

Proceedings Volume 10736, 1073604 (2018) https://doi.org/10.1117/12.2320651

KEYWORDS: Organic light emitting diodes, Molecules, Doping, Electrodes, Organic semiconductors, Metals, Alkali metals, Ions, Ionization, Semiconductors

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Proceedings Article | 19 September 2017 Presentation

The design and synthesis of n-dopants and TADF materials for OLED applications (Conference Presentation)

Seth Marder

Proceedings Volume 10362, 1036202 (2017) https://doi.org/10.1117/12.2276260

KEYWORDS: Organic light emitting diodes, Doping, Organic semiconductors, Flexible circuits, Semiconductor materials, Semiconductors, Electrodes, Fluorescent materials

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Proceedings Article | 15 August 2017 Open Access

Materials for third order nonlinear optics (Conference Presentation)

Seth Marder, Iryna Davydenko, Yulia Getmanenko, Janos Simon, Yadong Zhang, Joel Hales, Hyeongeu Kim, Taylor Allen, San-Hui Chi, Victor Khrustalev, Evgheni Jucov, Tatiana Timofeeva, Timothy Parker, Stephen Barlow, Joseph Perry

Proceedings Volume 9994, 999409 (2017) https://doi.org/10.1117/12.2244673

KEYWORDS: Nonlinear optical materials, Nonlinear optics, Organic materials, Signal attenuation, Telecommunications, Molecules, Molecular aggregates, Bridges, Molecular bridges, Thin film devices

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Proceedings Article | 4 November 2016 Presentation

Recent advances in the science and engineering of organic light-emitting diodes (Conference Presentation)

Bernard Kippelen, Michael Gaj, Xiaoqing Zhang, Sangmoo Choi, Canek Fuentes-Hernandez, Yadong Zhang, Stephen Barlow, Seth Marder, Walter Voit, Andrew Wei

Proceedings Volume 9941, 99410C (2016) https://doi.org/10.1117/12.2238213

KEYWORDS: Organic light emitting diodes, Luminescence, Singular optics, Internal quantum efficiency, Platinum, Shape memory polymers, Smart materials, Glasses, Polymers, Diodes

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Proceedings Article | 27 February 2016 Paper

Efficient light emission from hybrid inorganic/organic semiconductor structures by energy level optimization

R. Schlesinger, F. Bianchi, S. Blumstengel, Björn Kobin, K. Moudgil, S. Barlow, S. Hecht, S. Marder, N. Koch

Proceedings Volume 9749, 974909 (2016) https://doi.org/10.1117/12.2217006

KEYWORDS: Organic semiconductors, Heterojunctions, Semiconductors, P-type semiconductors, Zinc oxide, Energy transfer, Quenching (fluorescence), Thin films, Excitons, Quantum wells, Picosecond phenomena, Neodymium, Interfaces

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Proceedings Article | 1 September 2015 Paper

Mid-infrared hyperbolic metamaterial based on graphene-dielectric multilayers

You-Chia Chang, Alexander Kildishev, Evgenii Narimanov, Che-Hung Liu, Chang-Hua Liu, Siyuan Zhang, Seth Marder, Zhaohui Zhong, Theodore Norris

Proceedings Volume 9544, 954417 (2015) https://doi.org/10.1117/12.2190367

KEYWORDS: Graphene, Metamaterials, Absorption, Gold, Dielectrics, Free space, Scattering, Mid-IR, Ellipsometry, Photonics

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Proceedings Article | 31 August 2015 Presentation + Paper

Top-gate organic field-effect transistors fabricated on shape-memory polymer substrates

Sangmoo Choi, Canek Fuentes-Hernandez, Cheng-Yin Wang, Andrew Wei, Walter Voit, Yadong Zhang, Stephen Barlow, Seth Marder, Bernard Kippelen

Proceedings Volume 9568, 95680A (2015) https://doi.org/10.1117/12.2188684

KEYWORDS: Field effect transistors, Glasses, Transistors, Polymers, Electronics, Gold, Electrodes, Dielectrics, Resistance, Ultraviolet radiation

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Proceedings Article | 7 March 2014 Paper

Optimization of the electronic third-order nonlinearity of cyanine-like molecules for all optical switching

Honghua Hu, Trenton Ensley, Matthew Reichert, Manuel Ferdinandus, Davorin Peceli, Olga Przhonska, Seth Marder, Alex K.- Jen, Joel Hales, Joseph Perry, David Hagan, Eric Van Stryland

Proceedings Volume 8983, 898303 (2014) https://doi.org/10.1117/12.2037003

KEYWORDS: Molecules, Absorption, Nonlinear optics, Adaptive optics, Switching, Dispersion, Refractive index, Photonics, Physics, Molecular photonics

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Proceedings Article | 11 May 2012 Paper

Four wave mixing in silicon hybrid and silicon heterogeneous micro photonic structures

S. Jakobs, Alexander Petrov, Manfred Eich, Joel Hales, Joseph Perry, Seth Marder, Virginie Nazabal, Petr Nemec

Proceedings Volume 8434, 84340P (2012) https://doi.org/10.1117/12.921696

KEYWORDS: Silicon, Waveguides, Polymers, Absorption, Silicon photonics, Four wave mixing, Refractive index, Chalcogenide glass, Cladding, Photonic microstructures

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SPIE Journal Paper | 12 March 2012

Charge photogeneration in donor/acceptor organic solar cells

Safa Shoaee, Tracey Clarke, Mattias Eng, Iain McCulloch, James Durrant, Chun Huang, Stephen Barlow, Seth Marder, Eva Espildora, Juan Luis Delgado, Nazario Martin, Bert Campo, Dirk Vanderzande, Martin Heeney

JPE, Vol. 2, Issue 1, 021001, (March 2012) https://doi.org/10.1117/12.10.1117/1.JPE.2.021001

KEYWORDS: Polymers, Organic photovoltaics, Solar cells, Absorption, Excitons, Interfaces, Polarons, Energy efficiency, Polymer thin films, Fullerenes

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SPIE Journal Paper | 1 March 2011 Open Access

Deep in vivo two-photon imaging of blood vessels with a new dye encapsulated in pluronic nanomicelles

Mathieu Maurin, Olivier Stephan, Jean-Claude Vial, Seth Marder, Boudewijn van der Sanden

JBO, Vol. 16, Issue 03, 036001, (March 2011) https://doi.org/10.1117/12.10.1117/1.3548879

KEYWORDS: Blood, Tumors, Two photon imaging, In vivo imaging, Blood vessels, Luminescence, Plasma, Lung, Diffusion, Magnesium

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Proceedings Article | 2 September 2008 Paper

Highly efficient green phosphorescent organic light-emitting diodes with hybrid device geometry

Andreas Haldi, Benoit Domercq, Asha Sharma, Richard Hreha, Jian-Yang Cho, Seth Marder, Bernard Kippelen

Proceedings Volume 7051, 70510B (2008) https://doi.org/10.1117/12.795363

KEYWORDS: Organic light emitting diodes, External quantum efficiency, Ionization, Phosphorescent organic light-emitting diodes, Aluminum, Measurement devices, Glasses, Luminous efficiency, Telescopic pixel displays, Quantum efficiency

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Proceedings Article | 2 September 2008 Paper

Linear and nonlinear optical properties of highly transmissive one-dimensional metal-organic photonic bandgap structures

Canek Fuentes-Hernandez, Lazaro Padilha, Daniel Owens, Shuo-Yen Tseng, Scott Webster, Jian-Yang Cho, David Hagan, Eric Van Stryland, Seth Marder, Bernard Kippelen

Proceedings Volume 7049, 70490O (2008) https://doi.org/10.1117/12.797089

KEYWORDS: Copper, Absorption, Nonlinear optics, Transmittance, Metals, Refractive index, Dielectrics, Optical properties, Refraction, Polymers

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Proceedings Article | 11 February 2008 Paper

Polymer nanocomposite infiltration of silicon photonic crystals

Savaş Tay, Jayan Thomas, Babak Momeni, Murtaza Askari, Peter Hotchkiss, Simon Jones, Seth Marder, Ali Adibi, Robert Norwood, N. Peyghambarian

Proceedings Volume 6901, 690114 (2008) https://doi.org/10.1117/12.778568

KEYWORDS: Polymers, Nanocomposites, Nanoparticles, Photonic crystals, Refractive index, Crystals, Photorefractive polymers, Composites, Silicon photonics, Titanium dioxide

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Proceedings Article | 7 February 2008 Paper

Two-photon absorption in cross-shaped chromophores with phenylene-vinylene backbones

Mariacristina Rumi, Stephanie Pond, Qing Zhang, Maximilienne Bishop, Yadong Zhang, Stephen Barlow, Seth Marder, Joseph Perry

Proceedings Volume 6891, 689104 (2008) https://doi.org/10.1117/12.761818

KEYWORDS: Absorption, Molecules, Chromophores, Excitons, Argon, Luminescence, Oscillators, Electronics, Dendrimers, Spectroscopy

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Proceedings Article | 21 September 2005 Paper

Analysis of short-channel effects in organic field-effect transistors

Joshua Haddock, Xiaohong Zhang, Shijun Zheng, Seth Marder, Bernard Kippelen

Proceedings Volume 5940, 59400H (2005) https://doi.org/10.1117/12.615434

KEYWORDS: Field effect transistors, Transistors, Silicon, Modulation, Electrodes, Dielectrics, Crystals, Oxides, Nondestructive evaluation, Semiconductors

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Proceedings Article | 3 November 2004 Paper

Modeling of organic photovoltaic cells with large fill factor and high efficiency

Seunghyup Yoo, Benoit Domercq, Seth Marder, Neal Armstrong, Bernard Kippelen

Proceedings Volume 5520, (2004) https://doi.org/10.1117/12.564896

KEYWORDS: Solar cells, Organic photovoltaics, Resistance, Circuit switching, Diodes, Instrument modeling, Electrodes, Photovoltaics, Copper, Aluminum

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Proceedings Article | 26 October 2004 Paper

Near-infrared photorefractive polymer composites with high diffraction efficiency and fast response time

Jayan Thomas, Muhsin Eralp, Savas Tay, Guogiang Li, Seth Marder, Gerald Meredith, Axel Schulzgen, Robert Norwood, Nasser Peyghambarian

Proceedings Volume 5521, (2004) https://doi.org/10.1117/12.563829

KEYWORDS: Composites, Diffraction, Chromophores, Modulation, Absorption, Polymers, Birefringence, Photorefractive polymers, Telescopic pixel displays, Refractive index

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Proceedings Article | 26 October 2004 Paper

Trapping mechanisms and dynamics in bis-triarylamine-based photorefractive polymer composites

Canek Fuentes-Hernandez, Jayan Thomas, Gerald Meredith, Nasser Peyghambarian, Seth Marder, Bernard Kippelen

Proceedings Volume 5521, (2004) https://doi.org/10.1117/12.562924

KEYWORDS: Composites, Chromophores, Polymers, Absorption, Photorefractive polymers, Spectroscopy, Numerical simulations, Molecules, Thermal modeling, Solids

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Proceedings Article | 21 October 2004 Paper

Time-gated imaging through scattering media by using efficient THG in organic films

Gabriel Ramos-Ortiz, Myoungsik Cha, Stephen Barlow, Gregory Walker, Seth Marder, Bernard Kippelen

Proceedings Volume 5622, (2004) https://doi.org/10.1117/12.589419

KEYWORDS: Chromophores, Scattering media, Scattering, Photons, Absorption, Signal attenuation, Laser scattering, Optical parametric oscillators, Signal processing, Cameras

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Proceedings Article | 15 October 2004 Paper

Water-soluble 1,4-bis(4-aminostyryl)benzene derivatives for biological two-photon applications

Lisa Dollinger, Timothy Parker, Judith Lavin, Stephanie Pond, Mariacristina Rumi, Stephen Barlow, Joseph Perry, Seth Marder

Proceedings Volume 5516, (2004) https://doi.org/10.1117/12.561852

KEYWORDS: Chromophores, Luminescence, Solids, Chlorine, Silica, Quantum efficiency, Sodium, Argon, Absorption, Magnesium

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Proceedings Article | 16 February 2004 Paper

Organic light-emitting diodes based on arylamine molecules and polymers with a fluorene core

Benoit Domercq, Richard Hreha, Andreas Haldi, Stephen Barlow, Candace George, Seth Marder, Massimo Malagoli, Jean-Luc Bredas, Bernard Kippelen

Proceedings Volume 5214, (2004) https://doi.org/10.1117/12.506459

KEYWORDS: Molecules, Organic light emitting diodes, Telescopic pixel displays, Ionization, Luminescence, Bridges, Absorption, Glasses, Polymers, Temperature metrology

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Proceedings Article | 29 December 2003 Paper

High-sensitivity material systems for two-photon three dimensional microfabrication

Stephen Kuebler, Joseph Perry, Seth Marder, Christopher Ober, Kevin Braun, Tianyue Yu, Wenhui Zhou

Proceedings Volume 5347, (2003) https://doi.org/10.1117/12.532614

KEYWORDS: Microfabrication, Molecules, Absorption, Polymerization, Chemically amplified resists, Chromophores, Chemistry, Lithography, Optical lithography, 3D image processing

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Proceedings Article | 8 December 2003 Paper

Efficient photorefractive polymers sensitized by CdSe nanoparticles

Canek Fuentes-Hernandez, Duck Suh, Seth Marder, Bernard Kippelen

Proceedings Volume 5216, (2003) https://doi.org/10.1117/12.506620

KEYWORDS: Photorefractive polymers, Quantum dots, Nanoparticles, Holographic materials, Chromophores, Diffraction gratings, Four wave mixing, Diffraction

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Proceedings Article | 8 December 2003 Paper

Photorefractive polymers based on bis-triarylamine side-chain polymers

Canek Fuentes-Hernandez, Jayan Thomas, Roberto Termine, Muhsin Eralp, Michiharu Yamamoto, Kevin Cammack, Kenji Matsumoto, Stephen Barlow, Gregory Walker, Gerald Meredith, Nasser Peyghambarian, Bernard Kippelen, Seth Marder

Proceedings Volume 5216, (2003) https://doi.org/10.1117/12.506490

KEYWORDS: Polymers, Composites, Photorefractive polymers, Holographic materials, Chromophores, Modulation, Phase shift keying

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Proceedings Article | 16 September 2003 Paper

Information storage and retrieval using macromolecules as storage media

Masud Mansuripur, Pramod Khulbe, Stephen Kuebler, Joseph Perry, M. Giridhar, James Erwin, Kibyung Seong, Seth Marder, Nasser Peyghambarian

Proceedings Volume 5069, (2003) https://doi.org/10.1117/12.533057

KEYWORDS: Molecules, Data storage, Macromolecules, Particles, Electrodes, Binary data, Glasses, Liquids, Optical spheres, Optical storage

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Proceedings Article | 12 December 2002 Paper

Colorless molecular dopants for low-voltage operation of nematic liquid crystals

Joshua Haddock, Johanna Schmidtke, Sriram Kumaraswamy, David Mathine, Seth Marder, Bernard Kippelen

Proceedings Volume 4799, (2002) https://doi.org/10.1117/12.453308

KEYWORDS: Liquid crystals, Dielectrics, Anisotropy, Molecules, Crystals, Liquids, Absorption, LCDs, Capacitance, Doping

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Proceedings Article | 5 November 2002 Paper

Effect of aryl substitution on the hole mobility of bis-diarylaminobiphenyl-doped polymer composites

Jose-Luis Maldonado, Max Bishop, Canek Fuentes-Hernandez, Benoit Domercq, Stephen Barlow, S. Thayumanavan, Massimo Malagoli, Mariappan Manoharan, Jean-Luc Bredas, Seth Marder, Bernard Kippelen

Proceedings Volume 4802, (2002) https://doi.org/10.1117/12.453486

KEYWORDS: Molecules, Telescopic pixel displays, Polymers, Composites, Electrodes, Temperature metrology, Ionization, Picosecond phenomena, Glasses, Oxidation

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Proceedings Article | 4 November 2002 Paper

High-sensitivity two-photon photoacid generator for three-dimensional microfabrication

Stephen Kuebler, Kevin Braun, Wenhui Zhou, Tianyue Yu, J. Kevin Cammack, Christopher Ober, Seth Marder, Joseph Perry

Proceedings Volume 4809, (2002) https://doi.org/10.1117/12.453776

KEYWORDS: Polymerization, Microfabrication, Absorption, Molecules, Chromophores, Solids, Luminescence, Laser damage threshold, Quantum efficiency, Microelectromechanical systems

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Proceedings Article | 4 November 2002 Paper

One- and two-photon induced growth of ligand-coated nanoparticles for 2D and 3D metal patterning

Francesco Stellacci, Christina Bauer, Timo Meyer-Friedrichsen, Wim Wenseleers, Valerie Alain, Stephen Kuebler, Stephanie Pond, Yadong Zhang, Seth Marder, Joseph Perry

Proceedings Volume 4809, (2002) https://doi.org/10.1117/12.453771

KEYWORDS: Metals, Nanoparticles, Silver, Polymers, Magnesium, Composites, Nanocomposites, Electron beam lithography, Particles, Absorption

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Proceedings Article | 28 August 2002 Paper

New liquid crystal materials enabling revolutionary display devices

Julia Kornfield, Noel Clark, Larry Dalton, Seth Marder, Christopher Ober, Peter Palffy-Muhoray, Joseph Perry, Ned Thomas, David Walba, Shin-Tson Wu

Proceedings Volume 4712, (2002) https://doi.org/10.1117/12.480960

KEYWORDS: Liquid crystals, Polymers, Liquids, Crystals, Photonic crystals, LCDs, Electro optics, Analog electronics, Switching, Birefringence

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Proceedings Article | 13 June 2002 Paper

Photo-crosslinkable polymers as hole transport materials for organic light-emitting diodes

Benoit Domercq, D. Hrera, Nathalie Larribeau, Joshua Haddock, Seth Marder, Bernard Kippelen

Proceedings Volume 4642, (2002) https://doi.org/10.1117/12.470442

KEYWORDS: Polymers, Organic light emitting diodes, External quantum efficiency, Ultraviolet radiation, Optical lithography, Ionization, Quantum efficiency, Absorption, Thin films, Oxidation

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Proceedings Article | 15 June 2001 Paper

Optimization of photorefractive polymers doped with styrene-based chromophores

C. Fuentes-Hernandez, Jon Herlocker, J. Wang, Yadong Zhang, Seth Marder, Nasser Peyghambarian, Bernard Kippelen

Proceedings Volume 4279, (2001) https://doi.org/10.1117/12.429367

KEYWORDS: Polymers, Diffraction, Composites, Chromophores, Electrodes, Photorefractive polymers, Diffraction gratings, Four wave mixing, Refractive index, Modulation

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Proceedings Article | 17 April 2000 Paper

Three-dimensional microfabrication using two-photon-activated chemistry

Stephen Kuebler, Brian Cumpston, Sundaravel Ananthavel, Stephen Barlow, Jeffrey Ehrlich, L. Erskine, Ahmed Heikal, D. McCord-Maughon, J. Qin, Harold Roeckel, Maria Cristina Rumi, Seth Marder, Joseph Perry

Proceedings Volume 3937, (2000) https://doi.org/10.1117/12.382799

KEYWORDS: Polymerization, Absorption, Chromophores, Microfabrication, Ultraviolet radiation, 3D optical data storage, Luminescence, Polymers, 3D image processing, Scanning electron microscopy

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Proceedings Article | 18 May 1999 Paper

Recent development of highly efficient chromophores and polymers for electro-optic device applications

Alex K.Y. Jen, Hong Ma, Xiaoming Wu, Jianyao Wu, Sen Liu, Seth Marder, Larry Dalton, Ching-Fong Shu

Proceedings Volume 3623, (1999) https://doi.org/10.1117/12.348388

KEYWORDS: Chromophores, Polymers, Nonlinear optics, Absorption, Electro optic polymers, Electro optics, Chemistry, Analog electronics, Thin films, Optoelectronic devices

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Proceedings Article | 18 May 1999 Paper

Hybrid bilayer organic light-emitting devices based on high Tg hole transport polymers

Ghassan Jabbour, Sean Shaheen, Michael Morrell, Jeffrey Anderson, Paul Lee, Sankaran Thayumanavan, Stephen Barlow, Seth Marder, Erika Bellmann, Robert Grubbs, Bernard Kippelen, Neal Armstrong, Nasser Peyghambarian

Proceedings Volume 3623, (1999) https://doi.org/10.1117/12.348406

KEYWORDS: Organic light emitting diodes, Polymers, External quantum efficiency, Telescopic pixel displays, Luminous efficiency, Aluminum, Quantum efficiency, Ionization, Electrodes, Interfaces

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Proceedings Article | 16 December 1998 Paper

Electrochemical models for the radical annihilation reactions in organic light-emitting diodes

Neal Armstrong, Jeffrey Anderson, Paul Lee, Erin McDonald, R. Wightman, Hank Hall, Tracy Hopkins, Anne Padias, Sankaran Thayumanavan, Stephen Barlow, Seth Marder

Proceedings Volume 3476, (1998) https://doi.org/10.1117/12.332611

KEYWORDS: Organic light emitting diodes, Telescopic pixel displays, Molecules, Polymers, Luminescence, OLED lighting, Heterojunctions, Electroluminescence, Absorbance, Oxidation

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Proceedings Article | 16 December 1998 Paper

Synthesis of high-Tg hole-transporting polymers with different redox potentials and their performance in organic two-layer LEDs

Erika Bellmann, Sean Shaheen, Seth Marder, Bernard Kippelen, Robert Grubbs, Nasser Peyghambarian

Proceedings Volume 3476, (1998) https://doi.org/10.1117/12.332629

KEYWORDS: Polymers, Interfaces, Light emitting diodes, External quantum efficiency, Glasses, Telescopic pixel displays, Electroluminescence, Polymerization, Picosecond phenomena, Measurement devices

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Proceedings Article | 23 October 1998 Paper

Progress in organic photorefractive material development

Bernard Kippelen, Jon Herlocker, Jose-Luis Maldonado, Kyle Ferrio, Eric Hendrickx, Stephane Mery, A. Golemme, Seth Marder, Nasser Peyghambarian

Proceedings Volume 3471, (1998) https://doi.org/10.1117/12.328171

KEYWORDS: Liquid crystals, Molecules, Polymers, Diffraction, Photorefractive polymers, Birefringence, Anisotropy, Crystals, Liquids, Refractive index

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Proceedings Article | 1 September 1998 Paper

Three-dimensional microfabrication using two-photon polymerization

Brian Cumpston, Jeffrey Ehrlich, Stephen Kuebler, Matthew Lipson, Seth Marder, D. McCord-Maughon, Joseph Perry, Harold Roeckel, Maria Cristina Rumi

Proceedings Volume 3512, (1998) https://doi.org/10.1117/12.324052

KEYWORDS: Microelectromechanical systems, Bridges, 3D optical data storage, Polymers, Photopolymerization, Polymerization, Two photon polymerization, Chromophores, Microfabrication, Absorption

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Photopolymerization initiated by the simultaneous absorption of two photons is unique in its ability to produce complex three-dimensional (3D) structures from a single, thick photopolymer film. Strong 3D confinement of the polymerization process is not possible in other polymer microfabrication techniques such as LIGA, rapid prototyping, and conventional photoresist technology. Two-photon polymerization also permits the fabrication of 3D structures and the definition of lithographic features on non-planar surfaces. We have developed a wide array of chromophores which hold great promise for 3D microfabrication, as well as other applications, such as two-photon fluorescence imaging and 3D optical data storage. These materials are based on a donor- (pi) -donor, donor-acceptor-donor, or acceptor-donor-acceptor structural motif. The magnitude of the two-photon absorption cross-section, (delta) , and the position of the two-photon absorption maximum, (lambda) ⁽²)_max, can be controlled by varying the length of the conjugated bridge and by varying the strength of the donor/acceptor groups. In this way, chromophores have been developed which exhibit strong two- photon absorption in the range of 500 - 975 nm, in some cases as high as 4400 X 10^-50 cm⁴ s/photon-molecule. In the case of donor-(pi) -donor structures, quantum-chemical calculations show that the large absorption cross-sections arise from the symmetric re-distribution of charge from the donor end-groups to the conjugated bridge, resulting in an electronic excited-state which is more delocalized than the ground state. For many of these molecules, two-photon excitation populates a state which is sufficiently reducing that a charge transfer reaction can occur with acrylate monomers. The efficiency of these processes can be described using Marcus theory. Under suitable conditions, such reactions can induce radical polymerization of acrylate resins. Polymerization rates have been measured, and we show that these two-photon chromophores display increased sensitivity and recording speed over conventional photoinitiators. Complex 3D structures can be fabricated in acrylate films doped with these chromophores using tightly focused near-infrared femtosecond laser pulses. A 3D periodic array of polymeric columns has been produced for use in photonic bandgap applications. Tapered waveguide structures for interconnecting disparate-sized optical components have been constructed. More traditional MEMS structures, such as cantilevers, have also been produced. Such structures may be useful for organic vapor sensors. The two-photon photopolymerization process can be extended to other material systems, such as metallic, ceramic, and composite materials, by templating the photopolymer structures.

Proceedings Article | 17 August 1998 Paper

Synthesis and structural characterization of multifunctional polysiloxanes for photorefractive effect

Jun Li, Zhen Li, Caimao Zhan, Jingui Qin, Bernard Kippelen, Nasser Peyghambarian, Seth Marder

Proceedings Volume 3554, (1998) https://doi.org/10.1117/12.318125

KEYWORDS: Polymers, Photorefraction, Electro optics, Chromophores, Electro optic polymers, Platinum, Absorption, Infrared radiation, Lithium, Crystals

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Proceedings Article | 17 April 1998 Paper

High-gain photorefractive polymers

Eric Hendrickx, Jon Herlocker, Jose-Luis Maldonado, G. Guillemet, Harold Roeckel, L. Erskine, Seth Marder, Bernard Kippelen, Nasser Peyghambarian

Proceedings Volume 3281, (1998) https://doi.org/10.1117/12.305430

KEYWORDS: Composites, Diffraction, Polymers, Absorption, Photorefractive polymers, Crystals, Chromophores, Modulation, Four wave mixing, Glasses

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Proceedings Article | 9 October 1997 Paper

New advances in organic photorefractive material development

Bernard Kippelen, Boris Volodin, Derek Steele, Eric Hendrickx, NFN Sandalphon, Yasufumi Enami, Jose-Luis Maldonado, J. Wang, A. Golemme, H. Roeckel, Seth Marder, Bahram Javidi, Nasser Peyghambarian

Proceedings Volume 3144, (1997) https://doi.org/10.1117/12.290237

KEYWORDS: Photorefractive polymers, Chromophores, Polymers, Optical correlators, Light scattering, Diffraction, Liquids, Holography, Refractive index, Liquid crystals

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Proceedings Article | 1 November 1996 Paper

Structure/quadratic hyperpolarizability correlation: solvent effect

Marguerite Barzoukas, Jacques Muller, Alain Fort, Seth Marder, Valerie Alain, Mireille Blanchard-Desce

Proceedings Volume 2852, (1996) https://doi.org/10.1117/12.256168

KEYWORDS: Molecules, Absorption, Printed circuit board testing, Dielectric polarization, Polarizability, Dielectrics, Nonlinear optics, Chemical elements, Chromium, Lead

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Proceedings Article | 23 September 1994 Paper

Development of electro-optic polymers for high-voltage instrument transformers

Jorgen Skindhoj, Joseph Perry, Seth Marder

Proceedings Volume 2285, (1994) https://doi.org/10.1117/12.187507

KEYWORDS: Polymers, Electro optics, Epoxies, Electrodes, Sensors, Glasses, Birefringence, Thin films, Electrical breakdown, Modulation

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Proceedings Article | 15 May 1994 Paper

Experimental demonstration of the relationship between the second- and third-order polarizabilities of conjugated donor-acceptor molecules

Grant Bourhill, Lap-Tak Cheng, Christopher Gorman, Ging Lee, Seth Marder, Joseph Perry, M. Perry, Bruce Tiemann

Proceedings Volume 2143, (1994) https://doi.org/10.1117/12.173815

KEYWORDS: Polarizability, Molecules, Polarization, Raman spectroscopy, Harmonic generation, X-rays, Absorption, Chromophores, Crystallography, Electroluminescence

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Proceedings Article | 15 May 1994 Paper

Solid state optical limiting materials based on phthalocyanine-containing polymers and organically-modified sol-gels

Kamjou Mansour, Peter Fuqua, Seth Marder, Bruce Dunn, Joseph Perry

Proceedings Volume 2143, (1994) https://doi.org/10.1117/12.173824

KEYWORDS: Absorption, Polymethylmethacrylate, Optical limiting, Sol-gels, Polymers, Solids, Molecules, Quantum efficiency, Transmittance, Solid state electronics

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Proceedings Article | 15 May 1994 Paper

Progress on heteroaromatic chromophores in high-temperature polymers for electro-optic applications

Alex K.Y. Jen, Varanasi Rao, K. Drost, Yongming Cai, Robert Mininni, John Kenney, Edward Binkley, Larry Dalton, Seth Marder

Proceedings Volume 2143, (1994) https://doi.org/10.1117/12.173832

KEYWORDS: Chromophores, Nonlinear optics, Signal attenuation, Polymers, Cladding, Channel waveguides, Waveguides, Electro optics, Absorption, Metals

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Proceedings Article | 15 May 1994 Paper

Enhanced second-order optical nonlinearities in extended thiophene containing compounds

Sandra Gilmour, Seth Marder, Joseph Perry, Lap-Tak Cheng

Proceedings Volume 2143, (1994) https://doi.org/10.1117/12.173811

KEYWORDS: Chromophores, Molecules, Electro optics, Bridges, Polymers, Electrodes, Nonlinear optics, Modulation, Glasses, Aluminum

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Proceedings Article | 27 April 1993 Paper

Dynamics of optical limiting in heavy-atom-substituted phthalocyanines

Kamjou Mansour, Daniel Alvarez, Kelly Perry, Ingrid Choong, Seth Marder, Joseph Perry

Proceedings Volume 1853, (1993) https://doi.org/10.1117/12.144054

KEYWORDS: Absorption, Picosecond phenomena, Optical limiting, Molecules, Data modeling, Metalloids, Chemical species, Silicon, Optoelectronics, Nonlinear optics

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Proceedings Article | 27 April 1993 Paper

Third-order polarizabilities of symmetric and nonsymmetric polyene and cyanine-like organic molecules

Grant Bourhill, Kamjou Mansour, Bruce Tiemann, Christopher Gorman, Shawnna Biddle, Seth Marder, Joseph Perry

Proceedings Volume 1853, (1993) https://doi.org/10.1117/12.144063

KEYWORDS: Molecules, Optoelectronics, Solid state physics, Nickel, Raman spectroscopy, Liquids, Polarizability, Harmonic generation, Ranging, Crystals

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Proceedings Article | 27 April 1993 Paper

Synthesis and second-order nonlinear optical properties of various acceptor substituted biologically derived chromophores

Sandra Gilmour, Seth Marder, Bruce Tiemann, Lap-Tak Cheng

Proceedings Volume 1853, (1993) https://doi.org/10.1117/12.144067

KEYWORDS: Molecules, Chromophores, Polarizability, Raman spectroscopy, Solids, Harmonic generation, Optoelectronics, Carbon, Polarization, Bioalcohols

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Proceedings Article | 25 February 1993 Paper

Optimizing the second-order optical nonlinearities of organic molecules: asymmetric cyanines and highly polarized polyenes

Seth Marder, Christopher Gorman, Lap-Tak Cheng, Bruce Tiemann

Proceedings Volume 1775, (1993) https://doi.org/10.1117/12.139208

KEYWORDS: Carbon, Molecular bridges, Dielectric polarization, Polarizability, Nonlinear optics, Chemical species, Organic materials, Polarization, Chromophores, Molecules

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Proceedings Article | 7 December 1992 Paper

Synthesis and nonlinear optical properties of sol-gel materials containing phthalocyanines

Peter Fuqua, Kamjou Mansour, Daniel Alvarez, Seth Marder, Joseph Perry, Bruce Dunn

Proceedings Volume 1758, (1992) https://doi.org/10.1117/12.132042

KEYWORDS: Absorbance, Optical testing, Metals, Nonlinear optics, Solid state electronics, Molecules, Optical limiting, Silica, Absorption, Sol-gels

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Proceedings Article | 1 December 1991 Paper

Structure/property relationships for molecular second-order nonlinear optics

Seth Marder, Lap-Tak Cheng, Bruce Tiemann, David Beratan

Proceedings Volume 1560, (1991) https://doi.org/10.1117/12.50708

KEYWORDS: Polarization, Chromophores, Systems modeling, Chemical elements, Absorption, Nonlinear optics, Molecular bridges, Organic materials, Bridges, Molecules

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Proceedings Article | 1 December 1991 Paper

Organic salts with large electro-optic coefficients

Joseph Perry, Seth Marder, Kelly Perry, Edward Sleva, Christopher Yakymyshyn, Kevin Stewart, Eugene Boden

Proceedings Volume 1560, (1991) https://doi.org/10.1117/12.50727

KEYWORDS: Crystals, Second-harmonic generation, Electro optics, Nonlinear crystals, Chromophores, Organic materials, Absorption, Refractive index, Modulation, Dielectrics

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Showing 5 of 59 publications

Proceedings Volume Editor (1)

SPIE Conference Volume | 15 May 1994

Organic, Metallo-Organic, and Polymeric Materials for Nonlinear Optical Applications

Conference Committee Involvement (27)

Organic Photonic Materials and Devices XXVI

31 January 2024 | San Francisco, California, United States

Organic Photonic Materials and Devices XXV

1 February 2023 | San Francisco, California, United States

Organic Photonic Materials and Devices XXIV

26 January 2022 | San Francisco, California, United States

Organic Photonic Materials and Devices XXIII

6 March 2021 | Online Only, California, United States

Organic Photonic Materials and Devices XXII

5 February 2020 | San Francisco, California, United States

Organic Photonic Materials and Devices XXI

5 February 2019 | San Francisco, California, United States

Organic Photonic Materials and Devices XX

31 January 2018 | San Francisco, California, United States

Organic Photonic Materials and Devices XIX

30 January 2017 | San Francisco, California, United States

Organic Photonic Materials and Devices XVIII

15 February 2016 | San Francisco, California, United States

Organic Photonic Materials and Devices XVII

9 February 2015 | San Francisco, California, United States

Organic Photonic Materials and Devices XVI

3 February 2014 | San Francisco, California, United States

Organic Photonic Materials and Devices XV

4 February 2013 | San Francisco, California, United States

Organic Photonic Materials and Devices XIV

23 January 2012 | San Francisco, California, United States

Organic Photonic Materials and Devices XIII

24 January 2011 | San Francisco, California, United States

Organic Photonic Materials and Devices XII

26 January 2010 | San Francisco, California, United States

Organic Photonic Materials and Devices XI

27 January 2009 | San Jose, California, United States

Organic Photonic Materials and Devices X

22 January 2008 | San Jose, California, United States

Organic Photonic Materials and Devices IX

21 January 2007 | San Jose, California, United States

Nonlinear Optical Transmission and Multiphoton Processes in Organics IV

14 August 2006 | San Diego, California, United States

Organic Photonic Materials and Devices VIII

23 January 2006 | San Jose, California, United States

Nonlinear Optical Transmission and Multiphoton Processes in Organics III

2 August 2005 | San Diego, California, United States

Organic Photonic Materials and Devices VII

24 January 2005 | San Jose, California, United States

Nonlinear Optical Transmission and Multiphoton Processes in Organics II

5 August 2004 | Denver, Colorado, United States

Organic Photonic Materials and Devices VI

27 January 2004 | San Jose, CA, United States

Nonlinear Optical Transmission and Multiphoton Processes in Organics

3 August 2003 | San Diego, California, United States

Organic Photonic Materials and Devices V

27 January 2003 | San Jose, CA, United States

Organic, Metallo-Organic, and Polymeric Materials for Nonlinear Optical Applications

25 January 1994 | Los Angeles, CA, United States

Showing 5 of 27 Conference Committees

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